The correct option is this: EFFUSION BECAUSE THERE IS A MOVEMENT OF A GAS THROUGH A SMALL OPENING INTO A LARGER VOLUME.
Effusion refers to the movement of gas particles through a small hole. According to Graham's law, the effusion rate of a gas is inversely proportional to the square root of the mass of its particles.
Larger gases produces more spectral lines than the smaller gases because they have more orbitals in their atoms.
Hydrogen has only one orbital in which an electron orbits. At the excited state, that is, when the electron gains energy, the number of energy level it can transcend is very few. For larger elements, they have more orbitals and when excited, they can move from the ground state to other energy levels at which they produce various unique spectral lines.
NaHCO3 is the right answer