Product are favored at ...
example 2A + 3B = 5C + D if reaction is exothermic ....delta H = NEGATIVE)
A decrease in temperature favors the forward reaction (more product formed)
as heat is considered as a product
For the exam I have given: A decrease in pressure (volume increases as pressure decreases) .... there are more number of moles on the product side (6 in all) .....so according to LCP decreasing pressure will revert back to increase pressure and to do that equilibrium position shifts to the right (product)
decreasing concentration of product will cause a disturbance in equilibrium position....and reaction will restore its equilibrium by shifting to the right
(I believe its like this)
A positive cahnge of enthalpy, ΔH rxn = + 55 kJ/mol, for the forward reaction means that the reaction is endothermic, i.e. the reactants absorb energy and the products are higher in energy.
Activation energy is the difference in the energy level of the reactants and the peak in the potential energy diagram (the energy of the transition state).
For an endothermic reaction, the products will be closer in energy to the transition state than what the reactans will be; so, the activation energy of the reversed reaction is lower than the activation energy of the forward reaction.
Activation energy of reverse and forward reactions is related by:
Activation energy of reverse rxn = Activation energy of forward rxn - ΔH rxn
=> Activiation energy of reverse rxn = 102 kJ/mol - 55 kJ/mol = 47 kJ/mol
Answer: 47 kJ/mol
Answer:
See below.
Explanation:
CH3CH2CH2CH2OH is butanol.
The carboxylic acid formed , butyric acid has the formula:
CH3CH2CH2COOH.
Structural formula:
H H H O
| | | ||
H - C - C - C - C - OH
| | |
H H H
ΔSsys and ΔSsurr both have values larger than 0.
<h3>Entropy Change: What Is It?</h3>
- Entropy change is a phenomena that measures the evolution of randomness or disorder in a thermodynamic system.
- It has to do with how heat or enthalpy is converted during work.
- More unpredictability in a thermodynamic system indicates high entropy.
- Heat transport (delta Q) divided by temperature equals the change in entropy (delta S).
<h3>What causes variations in entropy?</h3>
- When a substance is divided into several pieces, entropy rises.
- Because the solute particles are split apart when a solution is generated, the dissolving process increases entropy.
- As the temperature rises, entropy increases.
learn more about entropy change here
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