Answer:
CH₃CH₂CH₂COOH > CH₃CH₂COOH > ClCH₂CH₂COOH > ClCH₂COOH
Explanation:
Electron-withdrawing groups (EWGs) increase acidity by inductive removal of electrons from the carboxyl group.
Electron-donating groups (EDGs) decrease acidity by inductive donation of electrons to the carboxyl group.
- The closer the substituent is to the carboxyl group, the greater is its effect.
- The more substituents, the greater the effect.
- The effect tails off rapidly and is almost zero after about three C-C bonds.
CH₃CH₂-CH₂COOH — EDG — weakest — pKₐ = 4.82
CH₃-CH₂COOH — reference — pKₐ = 4.75
ClCH₂-CH₂COOH — EWG on β-carbon— stronger — pKₐ = 4.00
ClCH₂COOH — EWG on α-carbon — strongest — pKₐ = 2.87
We have been given the condition that carbon makes up 35%
of the mass of the substance and the rest is made up of oxygen. With this, it
can be concluded that 65% of the substance is made up of oxygen. If we let x be
the mass of oxygen in the substance, the operation that would best represent
the scenario is,
<span> x = (0.65)(5.5 g)</span>
<span> <em> </em><span><em>x =
3.575 g</em></span></span>
Explanation:
The <u>First Law of Thermodynamics</u> states that energy cannot be created or destroyed in an isolated system. In other words, energy can be converted from one form into another, but it cannot be created nor destroyed.
<u>Conduction</u> is the transfer of energy from one molecule to another by direct contact. This transfer occurs when molecules hit against each other, which can take place in solids, liquids, and gases.
When you put your cold hands under your legs to warm your hands up, the heat energy from your legs is being transferred to your hands through conduction. However, since energy cannot be created, there is no extra heat energy that can instantaneously replace the heat created by your legs.