We will use this two reaction equation:
H2SO3 + H2O ↔ H3O+ + HSO3- Ka1 = 1.3 x 10^-2
HSO3- + H2O ↔ H3O+ + SO3 2- Ka2= 6.3 x 10^-8
we will use the ICE table for the first equation:
H2SO3 + H2O ↔ H3O+ + HSO3-
initial 0.025 0 0
change -X +X +X
Equ (0.025-X) X X
Ka1 = [H3O+] [HSO3-] / [H2SO3]
1.3 x 10^-2 = X^2 / (0.025 - X) by solving for X
∴ X = 0.0127
when [H3O+] = X
∴[H3O+] = 0.0127 M
and when [HSO3-] = X
∴[HSO3-] = 0.0127 M
and when [H2SO3] = 0.025 - X
∴[H2SO3] = 0.025 - 0.0127
= 0.0123 M
when Kw = [OH-][H3O+]
and Kw = 1.1 x 10^-14 / 0.0127
∴[OH-] = 1.1 x 10^-14 / 0.0127
= 8.66 x 10^-13 M
- by using the ICE table for the second equation:
HSO3- + H2O ↔ H3O+ + SO3 2-
initial 0.0127 0.0127 0
change -X +X +X
Equ (0.0127-X) (0.0127+X) X
when Ka2 = [SO32-] [H3O+] / [HSO3-]
by substitution:
6.3 x 10^-8 = X(0.0127+X) / (0.0127-X)
as the Ka2 is so small so we can assume that (0.01271 + X) & (0.01271-X) = 0.01271 and neglect X
6.3 x 10^-8 = 0.0127X /0.0127
∴X = 6.3 x 10^-8
when [SO3 2-] = X
∴[SO32-] = 6.3 x 10^-8
It is endothermic and the ∆H = +393.5 kJ.
Answer:
B- gravity
Explanation:
Gravity is a force in which everything in the universe is trying to pull everyother thing towards themsef. Here, the sun's gravity keeps the planet in orbit.
I hope im right! !!
Answer:
The answer to your question is M = 36.49 g
Explanation:
Data
mass = 8.21 g
volume = 4.8064 L
Temperature = 200°C
Pressure = 1.816 atm
M = ?
Process
1.- Convert temperature to °K
°K = 273 + 200
°K = 473
2.- Calculate the number of moles
n = (PV)/RT
n = (1.816)(4.8064)/(0.082)(473)
n = 0.225
3.- Calculate the molar mass
M --------------- 1 mol
8.21 g ---------- 0.225 moles
M = (1 x 8.21)/0.225
M = 36.49 g