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myrzilka [38]
3 years ago
13

PLEASE HELP it’s due in 30 minutes

Chemistry
1 answer:
Nady [450]3 years ago
6 0

Answer:

1-6

3 1 3 3 2 2

Explanation:

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Equal molar quantities of Ca2 and EDTA (H4Y) are added to make a 0.010 M solution of CaY2- at pH 10. The formation constant for
abruzzese [7]

Answer:

the concentration of free Ca2⁺ in this solution is 7.559 × 10⁻⁷

Explanation:

Given the data in the question;

Ca^{2+ + y^{4- ⇄  CaY^{2-

Formation constant Kf

Kf = CaY^{2- / ( [Ca^{2+][y^{4-] ) = 5.0 × 10¹⁰

Now,

[y^{4-] = \alpha _4CH_4Y; ∝₄ = 0.35

so the equilibrium is;

Ca^{2+ + H_4Y ⇄  CaY^{2- + 4H⁺

Given that; CH_4Y = Ca^{2+     { 1 mol Ca^{2+  reacts with 1 mol H_4Y  }

so at equilibrium, CH_4Y = Ca^{2+ = x

∴

Ca^{2+ + y^{4- ⇄  CaY^{2-

x        + x         0.010-x

since Kf is high, them x will be small so, 0.010-x is approximately 0.010

so;

Kf = CaY^{2- / ( [Ca^{2+][y^{4-] ) =  CaY^{2- / ( [Ca^{2+][\alpha _4CH_4Y] )  = 5.0 × 10¹⁰

⇒ CaY^{2- / ( [Ca^{2+][\alpha _4CH_4Y] )  = 5.0 × 10¹⁰

⇒ 0.010 / ( [x][ 0.35 × x] )  = 5.0 × 10¹⁰

⇒ 0.010 / 0.35x²  = 5.0 × 10¹⁰

⇒ x² = 0.010 / ( 0.35 × 5.0 × 10¹⁰ )

⇒ x² = 0.010 / 1.75 × 10¹⁰

⇒ x² = 0.010 / 1.75 × 10¹⁰

⇒ x² = 5.7142857 × 10⁻¹³

⇒ x = √(5.7142857 × 10⁻¹³)

⇒ x = 7.559 × 10⁻⁷

Therefore, the concentration of free Ca2⁺ in this solution is 7.559 × 10⁻⁷

8 0
2 years ago
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