The equation is already balanced.
B.
The cynobacteria were already there without the oxygen, so that rules out A, and a lot of prokaryotes were anaerobic, so that rules out C. Finally, Photosynthesis does not require oxygen. Instead, Oxygen is a waste product of it. Therefore, it cannot be D. So, we are only left with B
Hoped this helped :D
<span>a pure substance that can be separated into different elements by chemical means</span>