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Lelu [443]
3 years ago
15

The rearrangement which most likely occurs in the following reaction can be described as a

Chemistry
1 answer:
otez555 [7]3 years ago
5 0

Answer:

b. hydride shift from C-3 to C-2.

Explanation:

Markovnikov's rule states that *in the addition of a protic acid HX or other polar reagent to an asymmetric alkene, the acid hydrogen (H) or electropositive part gets attached to the carbon with more hydrogen substituents, and the halide (X) group or electronegative part gets attached to the carbon with more alkyl substituents* (wikipedia).

This rule implies that the hydrogen of HBr will be attached to C-1 and the carbocation will be on C-2. Remember that the order of stability of carbocations is tertiary > secondary > primary > methyl. A hydride shift can yield a tertiary carbocation.

C-3 is a tertiary carbon atom. If the hydride on carbon 3 shifts to carbon 2, a tertiary and more stable carbocation is formed. This accounts for the major product in the reaction.

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Explanation:

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             Option-A. Covalent bonds would need to form between the molecules.

Explanation:

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                   Polymerization reactions are those reactions in which small molecules called as monomers join together to form a large molecule also known as polymers. These reactions are done via different mechanisms like addition reaction, condensation reactions e.t.c.

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              Polybutene (polymer) is made up of 1-butene (monomers) through addition reaction in which the double bonds of 1-butene molecules are involved in the formation of new single covalent bond via acid catalyzed, base catalyzed or free radical mechanisms.

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In above equation "n" represent large number, H₂C=CH-CH₂-CH₃ represent 1-Butene (monomer) and --[H₂C-CH(C₂H₅)]-n-- represent polybutene (polymer).

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