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Ipatiy [6.2K]
3 years ago
11

5. A 5.00 g sample of an unknown substance was heated from 25.2 C to 55.1 degrees * C , and it required 133 to do so. Identify t

he unknown substance using the chart above.
show work please
Chemistry
1 answer:
Leviafan [203]3 years ago
7 0

Answer:

Aluminum

Explanation:

Given

T_1 = 25.2^oC

T_2 = 55.1^oC

m = 5.00g

\triangle Q= 133J

<em>See attachment for chart</em>

Required

Identify the unknown substance

To do this, we simply calculate the specific heat capacity from the given parameters using:

c = \frac{\triangle Q}{m\triangle T}

This gives:

c = \frac{\triangle Q}{m(T_2 - T_1)}

So, we have:

c = \frac{133J}{5.00g * (55.1C - 25.2C)}

c = \frac{133J}{5.00g * 29.9C}

c = \frac{133J}{149.5gC}

c = 0.89\ J/gC

From the attached chart, we have:

Al(s) = 0.89\ J/gC --- The specific heat capacity of Aluminum

<em>Hence, the unknown substance is Aluminum</em>

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1 ) Δs ( entropy change for hot block ) = - Q / th  ( -ve shows heat lost to cold block )

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<u>1) To show that heat flows spontaneously from high temperature to low temperature </u>

example :

Pick two(2) solid metal blocks with varying temperatures ( i.e. one solid block is hot and the other solid block is cold )

Place both blocks for time (t ) in an insulated system to reduce heat loss or gain to or from the environment

Check the temperature of both blocks after time ( t ) it will be observed that both blocks will have same temperature after time t ( first law of thermodynamics )

Δs ( entropy change for hot block ) = - Q / th  ( -ve shows heat lost to cold block )

Δs ( entropy change for cold block ) = Q / tc

∴ Total Δs = ΔSc + ΔSh

                 = Q/tc - Q/th

<u>2) Entropy change for Decomposition of mercuric oxide </u>

2HgO (s) → 2Hg(l) + O₂ (g)

Δs = positive

there is transition from solid to liquid and the melting point of mercury ( the point at which reaction will take place ) = 500⁰C

hence ΔSdecomposition = S⁻ Hg  -  S⁻ HgO =

Δh of reaction = 181.6 KJ

Temp = 500 + 273 = 773 k

hence ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k

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