Answer: Rate law=![k[A]^1[B]^2](https://tex.z-dn.net/?f=k%5BA%5D%5E1%5BB%5D%5E2)
, order with respect to A is 1, order with respect to B is 2 and total order is 3. Rate law constant is 
Explanation: Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.
![Rate=k[A]^x[B]^y](https://tex.z-dn.net/?f=Rate%3Dk%5BA%5D%5Ex%5BB%5D%5Ey)
k= rate constant
x = order with respect to A
y = order with respect to A
n = x+y = Total order
a) From trial 1: ![1.2\times 10^{-2}=k[0.10]^x[0.20]^y](https://tex.z-dn.net/?f=1.2%5Ctimes%2010%5E%7B-2%7D%3Dk%5B0.10%5D%5Ex%5B0.20%5D%5Ey)
(1)
From trial 2: ![4.8\times 10^{-2}=k[0.10]^x[0.40]^y](https://tex.z-dn.net/?f=4.8%5Ctimes%2010%5E%7B-2%7D%3Dk%5B0.10%5D%5Ex%5B0.40%5D%5Ey)
(2)
Dividing 2 by 1 :![\frac{4.8\times 10^{-2}}{1.2\times 10^{-2}}=\frac{k[0.10]^x[0.40]^y}{k[0.10]^x[0.20]^y}](https://tex.z-dn.net/?f=%5Cfrac%7B4.8%5Ctimes%2010%5E%7B-2%7D%7D%7B1.2%5Ctimes%2010%5E%7B-2%7D%7D%3D%5Cfrac%7Bk%5B0.10%5D%5Ex%5B0.40%5D%5Ey%7D%7Bk%5B0.10%5D%5Ex%5B0.20%5D%5Ey%7D)
therefore y=2.
b) From trial 2: (3)
From trial 3: ![9.6\times 10^{-2}=k[0.20]^x[0.40]^y](https://tex.z-dn.net/?f=9.6%5Ctimes%2010%5E%7B-2%7D%3Dk%5B0.20%5D%5Ex%5B0.40%5D%5Ey)
(4)
Dividing 4 by 3:![\frac{9.6\times 10^{-2}}{4.8\times 10^{-2}}=\frac{k[0.20]^x[0.40]^y}{k[0.10]^x[0.40]^y}](https://tex.z-dn.net/?f=%5Cfrac%7B9.6%5Ctimes%2010%5E%7B-2%7D%7D%7B4.8%5Ctimes%2010%5E%7B-2%7D%7D%3D%5Cfrac%7Bk%5B0.20%5D%5Ex%5B0.40%5D%5Ey%7D%7Bk%5B0.10%5D%5Ex%5B0.40%5D%5Ey%7D)
, x=1
Thus rate law is ![Rate=k[A]^1[B]^2](https://tex.z-dn.net/?f=Rate%3Dk%5BA%5D%5E1%5BB%5D%5E2)
Thus order with respect to A is 1 , order with respect to B is 2 and total order is 1+2=3.
c) For calculating k:
Using trial 1: ![1.2\times 10^{-2}=k[0.10]^1[0.20]^2](https://tex.z-dn.net/?f=1.2%5Ctimes%2010%5E%7B-2%7D%3Dk%5B0.10%5D%5E1%5B0.20%5D%5E2)
.
Explanation:
Ionic equation
NaCl(aq) --> Na+(aq) + Cl-(aq)
Na2SO4(aq) --> 2Na+(aq) + SO4^2-(aq)
In NaCl solution, 1 mole of Na+ is dissociated in 1 liter of solution while in Na2SO4, 2 moles of Na+ is dissociated in 1 liter of solution.
Molecular weight of NA2SO4 = (23*2) + 32 + (16*4)
= 142 g/mol
Molecular weight of NaCl = 23 + 35.5
= 58.5 g/mol
Masses
% Mass of NA+ in Na2SO4 = mass of Na+/total mass of Na2SO4 * 100
= 46/142 * 100
= 32.4%
% Mass of NA+ in NaCl = mass of Na+/total mass of NaCl * 100
= 23/58.5 * 100
= 39.3%
Therefore, the % mass of Na+ in NaCl and Na2SO4 are different so it cannot be used.
Answer:
14.93 g
Explanation:
First we <u>convert 1.2 x 10²³ atoms of arsenic (As) into moles</u>, using <em>Avogadro's number</em>:
- 1.2 x 10²³ atoms ÷ 6.023x10²³ atoms/mol = 0.199 mol As
Then we can<u> calculate the mass of 0.199 moles of arsenic</u>, using its<em> molar mass</em>:
- 0.199 mol * 74.92 g/mol = 14.93 g
Thus, 1.2x10²³ atoms of arsenic weigh 14.93 grams.
