<span>Van der waals interactions are the electrical interactions between two or more atoms and even molecules but the inter-molecular attractions between the molecules are not exactly strong, in fact they are the weakest. And these Van der waals interactions are happened when electrons are not symmetrical distributed in a molecule.</span>
The vapor pressure of a solution will decrease and the freezing point will decrease with an <span>increasing</span> in the amount of dissolved solute. So the answer is third option.