Answer: norfenefrine
Explanation:
Depression in freezing point is given by:

= Depression in freezing point
i= vant hoff factor = 1 (for non electrolyte)
= freezing point constant = 
m= molality

Weight of solvent (ethanol)= 
Molar mass of unknown non electrolyte = M g/mol
Mass of unknown non electrolyte added = 82 mg = 0.082 g (1g=1000mg)


The molecular mass of norfenefrine
is near to 154 and thus the identity of the white powder is norfenefrine .
Percentage by mass = (mass of substance / total mass) x 100
= 1.82 / (1.05 + 0.69 + 1.82) x 100
= 51.1% if Calcium Carbonate
Answer: The value of the equilibrium constant for this reaction is 
Explanation:
To calculate the moles, we use the equation:

Moles of
=
Moles of
= 
Moles of
=
Volume of solution = 2.7 L
Equilibrium concentration of
= 
Equilibrium concentration of
= 
Equilibrium concentration of
=
The given balanced equilibrium reaction is,
The expression for equilibrium constant for this reaction will be,
Now put all the given values in this expression, we get :

Thus the value of the equilibrium constant for this reaction is 