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Elena-2011 [213]
3 years ago
15

Question 4 (1 point)

Chemistry
1 answer:
sattari [20]3 years ago
6 0

Answer:

pH = 4.349

Explanation:

When HI is added to sodium acetate, CH3COONa, acetic acid is produced as follows:

CH3COONa + HI → CH3COOH + NaI

<em>That means the moles of HI added are the moles of acetic acid produced and the moles of sodium acetate consumed.</em>

<em>Moles of HI:</em>

0.0605L * (0.223mol/L) = 0.01349mol

To find pH of the buffer (Mixture of weak acid, acetic acid, and conjugate base, sodium acetate) we need to solve H-H euation:

pH = pKa + log [CH3COONa] / [CH3COOH]

<em>Where pKa is -log of Ka of the acid: -log1.8x10⁻⁵ = 4.745</em>

<em>And [] could be taken as moles of each specie</em>

<em />

<em>Moles CH3COONa:</em>

Inital moles: 0.086L * (0.385mol/L) = 0.03311

Final moles: 0.03311mol - 0.01349mol = 0.01962mol CH3COONa

<em>Moles CH3COOH:</em>

Inital moles: 0.086L * (0.410mol/L) = 0.03256

Final moles: 0.03256mol + 0.01349mol = 0.04875mol CH3COOH

pH = 4.745+ log [0.01962mol CH3COONa] / [0.04875mol CH3COOH]

pH = 4.3497

Rigth answer is:

<h3>4.349</h3>

<em />

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