Here we have to get the correct statements among the given, applicable for Diels-Alder reaction.
The true statements in case Diels-Alder reaction are-
1. An excess of Maleic anhydride is used.
2. The I.R. of the products are indistinguishable.
The Diels-Alder reaction is the most is the most important cyclo-addition reaction in organic chemistry. These are addition reactions in which ring systems are formed without eliminating any compounds.
There remains one diene and one dienophile. The reaction is reversible in nature and requires elevated temperature to obtain its transition state. The reaction rate become faster in certain condition like using of polar solvents.
Among the given statements the following statements are true-
1. An excess of maleic anhydride (the most effective di-enophile) is used to process the reaction in forward direction.
2. The products obtain in this reaction are stereoisomers thus are indistinguishable by infrared spectroscopy (IR).
The statements which are not true for the Diels-Alder reaction:
3. The re-crystallization of the products by any polar solvent like methanol is not feasible as it will cause the retro reaction due to stability of the transition state in polar solvent.
4. Cleaning of glassware are compulsory for any reaction it is not specifically true for Diels-Alder reaction.
5. The reaction occurs at elevated temperature thus flame is required.
You need the molercular mass of Sucrose.
You can either search the molecular formula of Sucrose and calculate the molecular mass, or search directly the molecular mass.
Here you have both:
Molecular mass of sucrose: 342.30 g / mol
Chemical formula of sucrose: C12 H22 O11 (if you want to just must multiply the number of each atom by its atomic mass to get the molecular mass).
Calculate the number of grams of O in that molecule:
O: 11 * 16.00 g/mol = 176.0 g of O.
Now use proportions:
176 g O / 342.30 g sucrose = x / 50.00 g sucrose
=> x = 50.00 g sucrose * 176.0 g O / 342.30 g sucrose =25.71 g O.
Answer: 25.17 g
Answer:
17. Yes, it represents a chemical reaction. This is because new substances were formed from the original substance.
18. (a) Formation of new substances
(b) Evolution or absorption of large quantity of heat
(c)Change in mass of substances
Explanation:
17. In the model above, molecules of a compound of carbon and hydrogen (molecular formula is C2H6) combines with molecular oxygen (O2) to produce two new substances; a compound composed of two oxygen atoms and one carbon atom (CO2) and another compound composed of two atoms of hydrogen and one atom of oxygen (H2O). Since the new substances formed are completely different from the original substances, it a chemical reaction. Also, a large volume of heat would have been given off.
18. To determine if a chemical reaction has occurred, the following observations can be looked out for.
a. Formation of new substances different entirely from the original substances
b. Evolution or absorption of large quantity of heat during the change. Check whether the vessel containing the substances gets hotter or colder.
c. Change in mass of substances. Since new substances are formed in a chemical reaction, there is usually a significant change in mass of the products and reactants.
Answer:
He developed the concept of concentric electron energy levels
Explanation:
Before Bohr's model, Rutherford's model was proposed. This model explains most of the properties of the atom but failed to explain the stability of the atom.
As per Rutherford's model, electrons revolve around the nucleus in the orbit.
But revolving electron in their orbit around nucleus would give up energy and so gradually move towards the nucleus and therefore, eventually collapse.
Bohr's proposed that the electrons around the nucleus move orbit of fixed energy called "stationary states". Electrons in these stationary states do not radiate energy.
Therefore, proposal of concentric electron energy levels refine the atomic models.
