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shepuryov [24]
3 years ago
15

Which of the following statements are True about the experimental process used in the Diels Alder reaction?

Chemistry
1 answer:
vovikov84 [41]3 years ago
8 0

Here we have to get the correct statements among the given, applicable for Diels-Alder reaction.

The true statements in case Diels-Alder reaction are-

1. An excess of Maleic anhydride is used.

2. The I.R. of the products are indistinguishable.

The Diels-Alder reaction is the most is the most important cyclo-addition reaction in organic chemistry. These are addition reactions in which ring systems are formed without eliminating any compounds.

There remains one diene and one dienophile. The reaction is reversible in nature and requires elevated temperature to obtain its transition state. The reaction rate become faster in certain condition like using of polar solvents.

Among the given statements the following statements are true-

1. An excess of maleic anhydride (the most effective di-enophile) is used to process the reaction in forward direction.

2. The products obtain in this reaction are stereoisomers thus are indistinguishable by infrared spectroscopy (IR).

The statements which are not true for the Diels-Alder reaction:

3. The re-crystallization of the products by any polar solvent like methanol is not feasible as it will cause the retro reaction due to stability of the transition state in polar solvent.

4. Cleaning of glassware are compulsory for any reaction it is not specifically true for Diels-Alder reaction.

5. The reaction occurs at elevated temperature thus flame is required.

 

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A single electron configuration can represent multiple atoms. The one below represents the following atoms with different charge
valentinak56 [21]

Answer:

To have the electronic configuration equal to 1s²2s²2p⁶3s²3p⁶4s²3d⁷, the chemical element must have an electrical charge equal to 27, that is, it must have 27 electrons, such as Cobalt (Co), for example.

Explanation:

The electronic configuration shown in the question above is known as the Linus Pauling distribution and represents the energy sub-levels that an electrically charged atom can have in relation to the amount of electrons it has.

The layers sub-levels are presented in the following order 1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d¹º 4p⁶ 5s² 4d¹º 5p⁶ 6s² 4f14 5d¹º 6p⁶ 7s² 5f14 6d¹º 7p⁶. Where the small numbers represent the number of electrons in each sub-level and the large numbers represent the layers of electronic distribution.

Accordingly, we can see that an atom that has the configuration 1s²2s²2p⁶3s²3p⁶4s²3d⁷ has 27 electrons, like Cobalt.

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