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nydimaria [60]
3 years ago
12

An object at 20∘C absorbs 25.0 J of heat. What is the change in entropy ΔS of the object? Express your answer numerically in jou

les per kelvin. ΔS = nothing J/K Request Answer Part E An object at 500 K dissipates 25.0 kJ of heat into the surroundings. What is the change in entropy ΔS of the object? Assume that the temperature of the object does not change appreciably in the process. Express your answer numerically in joules per kelvin. ΔS = nothing J/K Request Answer Part F An object at 400 K absorbs 25.0 kJ of heat from the surroundings. What is the change in entropy ΔS of the object? Assume that the temperature of the object does not change appreciably in the process. Express your answer numerically in joules per kelvin. ΔS = nothing J/K Request Answer Part G Two objects form a closed system. One object, which is at 400 K, absorbs 25.0 kJ of heat from the other object,which is at 500 K. What is the net change in entropy ΔSsys of the system? Assume that the temperatures of the objects do not change appreciably in the process. Express your answer numerically in joules per kelvin.
Chemistry
1 answer:
nevsk [136]3 years ago
7 0

Question:

Part D) An object at 20∘C absorbs 25.0 J of heat. What is the change in entropy ΔS of the object? Express your answer numerically in joules per kelvin.

Part E) An object at 500 K dissipates 25.0 kJ of heat into the surroundings. What is the change in entropy ΔS of the object? Assume that the temperature of the object does not change appreciably in the process. Express your answer numerically in joules per kelvin.

Part F) An object at 400 K absorbs 25.0 kJ of heat from the surroundings. What is the change in entropy ΔS of the object? Assume that the temperature of the object does not change appreciably in the process. Express your answer numerically in joules per kelvin.

Part G) Two objects form a closed system. One object, which is at 400 K, absorbs 25.0 kJ of heat from the other object,which is at 500 K. What is the net change in entropy ΔSsys of the system? Assume that the temperatures of the objects do not change appreciably in the process. Express your answer numerically in joules per kelvin.

Answer:

D) 85 J/K

E) - 50 J/K

F) 62.5 J/K

G) 12.5 J/K

Explanation:

Let's make use of the entropy equation: ΔS = \frac{Q}{T}

Part D)

Given:

T = 20°C = 20 +273 = 293K

Q = 25.0 kJ

Entropy change will be:

ΔS = \frac{25*1000}{293}

= 85 J/K

Part E)

Given:

T = 500K

Q = -25.0 kJ

Entropy change will be:

ΔS = \frac{-25*1000}{500}

= - 50 J/K

Part F)

Given:

T = 400K

Q = 25.0 kJ

Entropy change will be:

ΔS = \frac{25*1000}{400}

= 62.5 J/K

Part G:

Given:

T1 = 400K

T2 = 500K

Q = 25.0 kJ

The net entropy change will be:

ΔS = (\frac{25*1000}{400}) + (\frac{-25*1000}{500}

= 12.5 J/K

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The liquid to gas phase transition results in the largest increase in entropy.

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Consider a voltaic cell where the anode half-reaction is Zn(s) → Zn2+(aq) + 2 e− and the cathode half-reaction is Sn2+(aq) + 2 e
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<u>Answer:</u> The concentration of Sn^{2+} in the cell is 9.0\times 10^{-3}M

<u>Explanation:</u>

We are given:

<u>Oxidation half reaction:</u>  Zn(s)\rightarrow Zn^{2+}(aq.)+2e^-   E^o_{Zn^{2+}/Zn}=-0.76V

<u>Reduction half reaction:</u>  Sn^{2+}(aq.)+2e^-\rightarrow Sn(s)   E^o_{Sn^{2+}/Sn}=-0.136V

The substance having highest positive E^o potential will always get reduced and will undergo reduction reaction. Here, fluorine will undergo reduction reaction will get reduced.

Here, tin will undergo reduction reaction and will get reduced.

Oxidation reaction occurs at anode and reduction reaction occurs at cathode.

To calculate the E^o_{cell} of the reaction, we use the equation:

E^o_{cell}=E^o_{cathode}-E^o_{anode}

Putting values in above equation, we get:

E^o_{cell}=-0.136-(-0.76)=0.624V

To calculate the EMF of the cell, we use the Nernst equation, which is:

E_{cell}=E^o_{cell}-\frac{0.059}{n}\log \frac{[Mn^{2+}]}{[Cu^{2+}]}

where,

E_{cell} = electrode potential of the cell = 0.660 V

E^o_{cell} = standard electrode potential of the cell = +0.624 V

n = number of electrons exchanged = 2

[Zn^{2+}]=2.5\times 10^{-3}M

[Sn^{2+}] = ?

Putting values in above equation, we get:

0.660=0.624-\frac{0.059}{2}\times \log(\frac{2.5\times 10^{-3}}{[Sn^{2+}})

[Sn^{2+}]=9.0\times 10^{-3}M

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