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OLga [1]
2 years ago
10

Write the number below in scientific notation rounded off to 3 significant figures.

Chemistry
1 answer:
pychu [463]2 years ago
4 0

Answer:

0.000110

Explanation:

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(i) Based on the graph, determine the order of the decomposition reaction of cyclobutane at 1270 K. Justify your answer.
Leni [432]

Answer:

(c)(i) The order of the reaction based on the graph provided is first order.

(ii) 99% of the cyclobutane would have decomposed in 53.15 milliseconds.

d) Rate = K [Cl₂]

K = rate constant

The justification is presented in the Explanation provided below.

e) A catalyst is a substance that alters the rate of a reaction without participating or being used up in the reaction.

Cl₂ is one of the reactants in the reaction, hence, it participates actively and is used up in the process of the reaction, hence, it cannot be termed as a catalyst for the reaction.

So, this shows why the student's claim is false.

Explanation:

To investigate the order of a reaction, a method of trial and error is usually employed as the general equations for the amount of reactant left for various orders are known.

So, the behaviour of the plot of maybe the concentration of reactant with time, or the plot of the natural logarithm of the concentration of reactant with time.

The graph given is evidently an exponential function. It is a graph of the concentration of cyclobutane declining exponentially with time. This aligns with the gemeral expression of the concentration of reactants for a first order reaction.

C(t) = C₀ e⁻ᵏᵗ

where C(t) = concentration of the reactant at any time

C₀ = Initial concentration of cyclobutane = 1.60 mol/L

k = rate constant

The rate constant for a first order reaction is given

k = (In 2)/T

where T = half life of the reaction. It is the time taken for the concentration of the reactant to fall to half of its initial concentration.

From the graph, when the concentration of reactant reaches half of its initial concentration, that is, when C(t) = 0.80 mol/L, time = 8.0 milliseconds = 0.008 s

k = (In 2)/0.008 = (0.693/0.008) = 86.64 /s

(ii) Calculate the time, in milliseconds, that it would take for 99 percent of the original cyclobutane at 1270 K to decompose

C(t) = C₀ e⁻ᵏᵗ

when 99% of the cyclobutane has decomposed, there's only 1% left

C(t) = 0.01C₀

k = 86.64 /s

t = ?

0.01C₀ = C₀ e⁻ᵏᵗ

e⁻ᵏᵗ = 0.01

In e⁻ᵏᵗ = In 0.01 = -4.605

-kt = -4.605

t = (4.605/k) = (4.605/86.64) = 0.05315 s = 53.15 milliseconds.

d) The reaction mechanism for the reaction of cyclopentane and chlorine gas is given as

Cl₂ → 2Cl (slow)

Cl + C₅H₁₀ → HCl + C₅H₉ (fast)

C₅H₉ + Cl → C₅H₉Cl (fast)

The rate law for a reaction is obtained from the slow step amongst the the elementary reactions or reaction mechanism for the reaction. After writing the rate law from the slow step, any intermediates that appear in the rate law is then substituted for, using the other reaction steps.

For This reaction, the slow step is the first elementary reaction where Chlorine gas dissociates into 2 Chlorine atoms. Hence, the rate law is

Rate = K [Cl₂]

K = rate constant

Since, no intermediates appear in this rate law, no further simplification is necessary.

The obtained rate law indicates that the reaction is first order with respect to the concentration of the Chlorine gas and zero order with respect to cyclopentane.

e) A catalyst is a substance that alters the rate of a reaction without participating or being used up in the reaction.

Cl₂ is one of the reactants in the reaction, hence, it participates actively and is used up in the process of the reaction, hence, it cannot be termed as a catalyst for the reaction.

So, this shows why the student's claim is false.

Hope this Helps!!!

6 0
3 years ago
What is formed when two or more elements are bonded together?​
Nadusha1986 [10]

Answer:

a compound

Explanation:

a compound consists of two or more elements combined

6 0
2 years ago
Read 2 more answers
If chemical bonds didn’t
hram777 [196]

All of the above answers are true right answer is option D

because, no bond no molecule no interaction no life,

no bond= only element will exist

Energy would not exist coz energy consumption and excretion takes place during bond formation and bond breaking process!

3 0
3 years ago
Read 2 more answers
Vegetarian diets can provide high levels of antioxidants and a lipid profile that can help prevent coronary disease. However, th
Arada [10]

Answer:

The correct option is: "Vitamin B12 (cobalamin) is not found in the vegan diet and is very low in the lacto-vegetarian diet"

Explanation:

Homocysteine is a VERY IMPORTANT type of amino acid, a chemical that the body uses to make proteins. Normally, vitamin B12, vitamin B6, and folic acid break down homocysteine and transform it into other substances that the body needs. There should be very little homocysteine left in the bloodstream. If you have high homocysteine levels in your blood, that could be a sign of a vitamin deficiency of the vitamins listed above, a heart condition, or a rare inherited disorder.

8 0
3 years ago
Read 2 more answers
Consider the reaction.
Alex_Xolod [135]

Note the signs of equilibrium:-

  • Reaction don't procede forward or backward
  • Concentration of products and reactants remains same .

So

if

Concentration of A is 2M then concentration of B should be same .

So equilibrium constant K is 1

\\ \rm\rightarrowtail K=\dfrac{[Products]^a}{[Reactants]^b}

So

  • [B]=[A]^2
  • [B]=2^2
  • [B]=4M
8 0
2 years ago
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