PH of a solution will be <span>higher than 7
</span>
Ammonium cyanide is a salt formed by hydrogen cyanide and ammonia. Ammonia is a weak base and hydrogen cyanide is a weak acid.
NH₄CN + H₂O ⇒ NH₃ + HCN
NH₄⁺ + H₂O -----> H₃O⁺ + NH₃
CN⁻ + H₂O -----> HCN + OH⁻
Although both compounds are weak electrolytes, NH₃ is somewhat stronger base than HCN is a strong acid, so the solution reacts alkaline. We can prove this using Ka and Kb values:
Ka(HCN) = 4.9 x × 10⁻¹⁰
Kb(NH₃) = 1.8 × 10⁻⁵<span>
Kw= </span>1.0 × 10⁻¹⁴
Let's first calculate Ka for NH₄⁺:
Ka(NH₄⁺) x Kb(NH₃<span>) = pKw
</span>Ka(NH₄⁺) = Kw/Kb(NH₃) = 5.6 x 10⁻¹⁰
Then, Kb for CN⁻:
Kb(CN⁻) x Ka(HCN) = pKw
Kb(CN⁻) = Kw/Ka(HCN) = 2 x 10⁻⁵
From this, we can see that the acid constant NH4⁺ is much lower than the base constant of CN⁻, which will say that the solution of NH₄CN will react slightly alkaline because of the higher presence of hydroxyl ions in solution.
Answer:
97 J
Explanation:
Step 1: Given data
- Mass of the sample (m): 12 kg
- Specific heat capacity (c): 0.231 J/kg.°C (this can also be expressed as 0.231 J/kg.K)
- Initial temperature: 45 K
Step 2: Calculate the temperature change
ΔT = 80 K - 45 K = 35 K
Step 3: Calculate the heat required (Q)
We will use the following expression.
Q = c × m × ΔT
Q = 0.231 J/kg.K × 12 kg × 35 K = 97 J
compound name compound formula elements present
water H2O hydrogen (H) and oxygen (O)
ammonia NH3 nitrogen (N) and hydrogen (H)
carbon monoxide CO carbon (C) and oxygen (O)
carbon dioxide CO2 carbon (C) and oxygen (O)
