Answer:
28.20 mL of the stock solution.
Explanation:
Data obtained from the question include the following:
Molarity of stock solution (M1) = 12.1 M
Volume of diluted solution (V2) = 350.0 mL
Molarity of diluted solution (M2) = 0.975 M
Volume of stock solution needed (V1) =..?
The volume of stock solution needed can be obtained by using the dilution formula as shown below:
M1V1 = M2V2
12.1 x V1 = 0.975 x 350
Divide both side by 12.1
V1 = (0.975 x 350)/12.1
V1 = 28.20 mL.
Therefore, 28.20 mL of the stock solution will be needed to prepare 350.0 mL of 0.975 M HCl solution.
When a specific amount of energy is emitted when excited electrons in an atom in a sample of an element return to the ground state, this emitted energy can
<span>be used to determine the "identity of the element".</span>
Answer:
Explanation:
We can calculate the volume of the oxygen molecule as the radius of oxygen molecule is given as 2×10⁻¹⁰m.
We know that volume=4/3×πr³
volume =4/3×π(2.0×10⁻¹⁰m)³
volume=33.40×10⁻³⁰m³
Volume of oxygen molecule=33.40×10⁻³⁰m³
we know the ideal gas equation as:
PV=nRT
k=R/Na
R=k×Na
PV=n×k×Na×T
n×Na=N
PV=Nkt
p is pressure of gas
v is volume of gas
T is temperature of gas
N is numbetr of molecules
Na is avagadros number
k is boltzmann constant =1.38×10⁻²³J/K
R is real gas constant
So to calculate pressure using the formula;
PV=NkT
P=NkT/V
Since there is only one molecule of oxygen so N=1
P=[1×1.38×10⁻²³J/K×300]/[33.40×10⁻³⁰m³
p=12.39×10⁷Pascal
Answer:
56.9 mmoles of acetate are required in this buffer
Explanation:
To solve this, we can think in the Henderson Hasselbach equation:
pH = pKa + log ([CH₃COO⁻] / [CH₃COOH])
To make the buffer we know:
CH₃COOH + H₂O ⇄ CH₃COO⁻ + H₃O⁺ Ka
We know that Ka from acetic acid is: 1.8×10⁻⁵
pKa = - log Ka
pKa = 4.74
We replace data:
5.5 = 4.74 + log ([acetate] / 10 mmol)
5.5 - 4.74 = log ([acetate] / 10 mmol)
0.755 = log ([acetate] / 10 mmol)
10⁰'⁷⁵⁵ = ([acetate] / 10 mmol)
5.69 = ([acetate] / 10 mmol)
5.69 . 10 = [acetate] → 56.9 mmoles
Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
