Pls help i will mark you the brainlest

A 25.0 mL solution of 0.100 M CH3COOH is titrated with a 0.200 M KOH solution. Calculate the pH after the following additions of

zaharov [31]

Answer:

a) pH = 2.88

b) pH = 4.598

c) pH = 5.503

d) pH = 8.788

e) pH = 12.097

Explanation:

CH3COOH ↔ CH3COO- + H3O+

∴ Ka = 1.75 E-5 = [H3O+]*[CH3COO-] / [CH3COOH]

a) 0.0 mL KOH:

mass balance:

⇒ C CH3COOH = [CH3COOH] + [CH3COO-] = 0.100 M

charge balance:

⇒ [H3O+] = [CH3COO-]

⇒ 1.75 E-5 = [H3O+]²/(0.100 - [H3O+])

⇒ [H3O+]² + 1.75 E-5[H3O+] - 1.75 E-6 = 0

⇒ [H3O+] = 1.314 E.3 M

∴ pH = - Log [H3O+]

⇒ pH = 2.88

b) 5.0 mL KOH:

CH3COOH + KOH ↔ CH3COONa + H2O

∴ C CH3COOH = ((0.025)(0.100) - (5 E-3)(0.200))/(0.025+5 E-3)

⇒ C CH3COOH = 0.05 M

∴ C KOH = ((5 E-3)(0,200))/(0.025+5 E-3) = 0.033 M

mass balance:

⇒ C CH3COOH + C KOH = [CH3COOH] + [CH3COO-] = 0.05 + 0.033 = 0.083 M

charge balance:

⇒ [H3O+] + [K+] = [CH3COO-]

⇒ [CH3COO-] = [H3O+] + 0.033

⇒ 1.75 E-5 = ([H3O+]*([H3O+] + 0.033))/(0.083 - ([H3O+] + 0.033))

⇒ 1.75 E-3 = ([H3O+]² + 0.033[H3O+])/(0.05 - [H3O+])

⇒ 8.75 E-7 - 1.75 E-5[H3O+] = [H3O+]² + 0.033[H3O+]

⇒ [H3O+]² +0.03302[H3O+] - 8.75 E-7 = 0

⇒ [H3O+] = 2.523 E-5 M

⇒ pH = 4.598

equivalent point:

(C*V)acid = (C*V)base

⇒ (0.100 M)*(0.025 L) = (0.200 M)( Vbase)

⇒ Vbase = 0.0125L = 12.5 mL

c) 10.0 mL KOH:

∴ C CH3COOH = 0.0143 M

∴ C KOH = 0.057 M

as in the previous point, starting from the mass and charge balances, we obtain:

⇒ [H3O+] = 3.1386 E-6 M

⇒ pH = 5.503

d) 12.5 mL KOH:

at the equivalence point, there is complete salt formation, then the pH is calculated through the salt:

CH3COO- + H2O ↔ CH3COOH - OH-

∴ Kw/Ka = 1 E-14/1.75 E-5 = 5.714 E-10 = [CH3COOH]*[OH-]/[CH3COO-]

∴ [CH3COO-] = (0.025)(0.100))/(0.025+0.0125) = 0.066 M

mass balance:

⇒ 0.066 = [CH3COOH] + [CH3COO-]..........(1)

charge balance:

⇒ [K+] = [OH-] + [CH3COO-] = 0.066 M.........(2)

∴ [K+] = C CH3COO- = 0.066 M

(1) = (2):

⇒ [OH-] = [CH3COOH].......(3)

⇒ 5.714 E-10 = [OH-]² / (0.066 - [OH-])

⇒ [OH-]² + 5.714 E-10[OH-] - 3.7712 E-11 = 0

⇒ [OH-] = 6.1408 e-6 m

⇒ pOH = 5.212

⇒ pH = 14 - pOH = 8.788

d) 15.0 mL KOH:

after the equivalence point there is salt and excess base (OH-); ph is calculated from excess base:

⇒ C KOH = ((0.015)(0.200) - (0.025)(0.100)) / (0.025 + 0.015) = 0.0125 M

⇒ [OH-] ≅ C KOH = 0.0125 M

⇒ pOH = 1.903

⇒ pH = 12.097

8 0

3 years ago

You compare two layers to a because the crust and upper mantle are solid

balandron [24]

On the earth there is the top layer dirt then loam comes next

6 0

3 years ago

Passing an electric current through a sample of water (H2O) can cause the water to decompose into hydrogen gas (H2) and oxygen g

Andreas93 [3]

2H2O --> 2H2 + O2
The mole H2O:mole O2 ratio is 2:1
Now determine how many moles of O2 are in 50g: 50g × 1mol/32g = 1.56 moles O2
Since 1 mole of O2 was produced for every 2 moles of H2O, we need 2×O2moles = H2O moles
2×1.56 = 3.13 moles H2O
Finally, convert moles to grams for H2O:
3.13moles × 18g/mol = 56.28 g H2O
D) 56.28

7 0

3 years ago

2) what is the mass of 6.02 x 1023 atoms of arsenic?

zzz [600]

Data:
Arsenic Molar Mass = 74,9216 ≈ 75 u (atomic mass unit)

Solving:

1 mole of arsenic → 75g ------------ 6,02*10²³ molecules
..................................X -------------- 1 molecule

6,02*10²³X = 75
$x = \frac{75}{6,02*10^{23}}$
$\boxed{x \approx 1,24*10^{24}grams}$

6 0

2 years ago

Argon (Ar) and helium (He) are initially in separate compartments of a container at 25°C. The

love history [14]

Answer:

(a) $V_B=11.68L$

(b) $x_{He}=0.533$

Explanation:

Hello,

In this case, since the both gases behave ideally, with the given information we can compute the moles of He in A:

$n_A=\frac{0.082\frac{atm*L}{mol*K}*298K}{1.974 atm*6.00L}=2.063mol$

Thus, since the final pressure is 3.60 bar, we can write:

$P=x_{Ar}P_A+x_{He}P_B\\\\P=\frac{n_{Ar}}{n_{Ar}+n_{He}} P_A+\frac{n_{He}}{n_{Ar}+n_{He}} P_B\\\\3.60bar=\frac{2.063mol}{2.063mol+n_{He}} *2.00bar+\frac{n_{He}}{2.063mol+n_{He}} *5.00bar$

The moles of helium could be computed via solver as:

$n_{He}=2.358mol$

Or algebraically:

$3.60bar=\frac{1}{2.063mol+n_{He}} *(4.0126+5.00*n_{He})\\\\7.314+3.60n_{He}=4.013+5.00*n_{He}\\\\7.314-4.013=5.00*n_{He}-3.60n_{He}\\\\n_{He}=\frac{3.3}{1.4}=2.358mol$

In such a way, the volume of the compartment B is:

$V_B=\frac{n_{He}RT}{P_B}=\frac{2.358mol*0.082\frac{atm*L}{mol*K}*298.15K}{4.935atm}\\ \\V_B=11.68L$

Finally, he mole fraction of He is:

$x_{He}=\frac{2.358}{2.358+2.063}\\ \\x_{He}=0.533$

Regards.

8 0

2 years ago