Answer:
See explanation and images attached
Explanation:
a) In the mechanism for the acid catalysed esterification of propanoic acid using ethanol, we can see that the first step is the protonation of the acid followed by nucleophillic attack of the alcohol. Loss of water and consequent deprotonation regenerates the acid catalyst. We can see the fate of the 18O labelled ethanol in the mechanism shown.
b) In the second mechanism, an unnamed ester is hydrolysed using an acid catalyst. The attack of the acid and subsequent nucleophillic attack of water labelled with 18O leads to the incorporation of this 18O into the product acid as shown in the mechanism attached to this answer.
Answer:
The solution is 10^-2 or 0.01M in HCl.
Explanation:
meaning of pH is "power of hydrogen".
what is the molar concentration of a HCl solution with pH=2?
Let say pH=2
[H+]=10^-2M
HCL is a strong acid that dissociates completely:
[H+]=[HCL]
Therefore solution is 10^-2 or 0.01M in HCL.
Answer:
1) positive
2) carbocation
3) most stable
4) faster
Explanation:
A common test for the presence of alcohols can be achieved using the Lucas reagent. Lucas reagent is a mixture of concentrated hydrochloric acid and zinc chloride.
The reaction of Lucas reagent reacts with alcohols leading to the formation of an alkyl chloride. Since the reaction proceeds via a carbocation mechanism, tertiary alcohols give an immediate reaction. Once a tertiary alcohol is mixed with Lucas reagent, the solution turns cloudy almost immediately indicating an instant positive reaction.
Secondary alcohols may turn cloudy within five minutes of mixing the solutions. Primary alcohols do not significantly react with Lucas reagent obviously because they do not form stable carbocations.
Therefore we can use the Lucas reagent to distinguish between primary, secondary and tertiary alcohols.
Answer is: 4.45 grams of methane gas <span>need to be combusted</span>.
Balanced chemical reaction: CH₄ + 2O₂ → CO₂ + 2H₂O.
Ideal gas law: p·V =
n·R·T.<span>
p = 1.1 atm.
T = 301 K.
V(H</span>₂O) <span>= 12.5 L.
R = 0,08206 L·atm/mol·K.
</span>n(H₂O) = <span>1.1 atm ·
12.5 L ÷ 0,08206 L·atm/mol·K · 301 K.
</span>n(H₂O) = 0.556 mol.
From chemical reaction: n(H₂O) : n(CH₄) = 2 : 1.
n(CH₄) = 0.556 mol ÷ 2 = 0.278 mol.
m(CH₄) = 0.278 mol · 16 g/mol.
m(CH₄) = 4.448 g.
Because they can't get trapped in.
