Aluminum's outer electron in 3p-orbital is slightly further from the nucleus and protected by 3s-orbital. This causes it to need less energy. Magnesium's outer electron is closer and not protected by an outer orbital.
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Many food chains together create a food web.
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You have to use the molar volume of gas which is 22.4L/mol at STP. To find the number of moles of from a given volume of gas at STP, you need to divide the given volume by 22.4L/mol.
44.4L/22.4L/mol=1.98mol of gas