Answer:
option (B) decreases
Explanation:
According to the Wein's displacement law, the minimum wavelength of the radiated emission is inversely proportional to the absolute temperature of the body which emits radiation.

Where, T is the absolute temperature of the body and λm is the minimum wavelength of heat radiated.
Here, as the temperature increases, the wavelength decreases.
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The longest wavelength in the Molecule's absorption spectrum is 2250nm