PV = nRT
P = (nRT)/V
P = (0.3 mol × 0.08206 atm-l/(mol-K) × (273.15 + 30) K)/(0.5 l)
P = 14.9258934 atm
Answer : The energy removed must be, 29.4 kJ
Explanation :
The process involved in this problem are :
The expression used will be:
![Q=[m\times c_{p,l}\times (T_{final}-T_{initial})]+[m\times \Delta H_{fusion}]+[m\times c_{p,s}\times (T_{final}-T_{initial})]](https://tex.z-dn.net/?f=Q%3D%5Bm%5Ctimes%20c_%7Bp%2Cl%7D%5Ctimes%20%28T_%7Bfinal%7D-T_%7Binitial%7D%29%5D%2B%5Bm%5Ctimes%20%5CDelta%20H_%7Bfusion%7D%5D%2B%5Bm%5Ctimes%20c_%7Bp%2Cs%7D%5Ctimes%20%28T_%7Bfinal%7D-T_%7Binitial%7D%29%5D)
where,
= heat released for the reaction = ?
m = mass of benzene = 94.4 g
= specific heat of solid benzene = 
= specific heat of liquid benzene = 
= enthalpy change for fusion = 
Now put all the given values in the above expression, we get:
![Q=[94.4g\times 1.73J/g.K\times (279-322)K]+[94.4g\times -125.6J/g]+[94.4g\times 1.51J/g.K\times (205-279)K]](https://tex.z-dn.net/?f=Q%3D%5B94.4g%5Ctimes%201.73J%2Fg.K%5Ctimes%20%28279-322%29K%5D%2B%5B94.4g%5Ctimes%20-125.6J%2Fg%5D%2B%5B94.4g%5Ctimes%201.51J%2Fg.K%5Ctimes%20%28205-279%29K%5D)
Negative sign indicates that the heat is removed from the system.
Therefore, the energy removed must be, 29.4 kJ
Answer:
D. Number of electrons
Answer: -2.373 x 10^-24J/K(particles
Explanation: Entropy is defined as the degree of randomness of a system which is a function of the state of a system and depends on the number of the random microstates present.
The entropy change for a particle in a system depends on the initial and final states of a system and is given by Boltzmann equation as
S = k ln(W) .
where S =Entropy
K IS Boltzmann constant ==1.38 x 10 ^-23J/K
W is the number of microstates available to the system.
The change in entropy is given as
S2 -S1 = kln W2 - klnW1
dS = k ln (W2/W1)
where w1 and w2 are initial and final microstates
from the question, W2(final) = 0.842 x W1(initial), so:
= 1.38*10-23 ln (0.842)
=1.38*10-23 x -0.1719
= -2.373 x 10^-24J/K(particles)
