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andrezito [222]
2 years ago
6

How many mL of 0.150 M HF solution are required to produce 0.0370 moles of HF

Chemistry
1 answer:
stealth61 [152]2 years ago
4 0

Answer:

247 ml

Explanation:

How many mL of 0.150 M HF solution are required to produce 0.0370 moles of HF 0.150 moles/ liter = 0.150/1000 moles/ml =0.000150 moles/ml

0.000150 x ? = 0.0370 moles HF

? = 0.0370/0.000150 = 247 ml

check

247 ml = 247/1000 L = 0.247

(0.247) x (0.150) =0.370 check

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\large \boxed{\text{D.) 91 kPa}}

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We can use the Ideal Gas Law — pV = nRT

Data:

V = 15.0 L

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Calculation:

\begin{array}{rcl}pV & =& nRT\\p \times \text{15.0 L} & = & \text{0.55 mol} \times \text{8.31 kPa$\cdot$ L$\cdot$K$^{-1}$mol$^{-1}\times$ 300 K}\\15.0p & = & \text{1370 kPa}\\p & = & \textbf{91 kPa}\end{array}\\\text{The pressure in the container is $\large \boxed{\textbf{91 kPa}}$}

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Write the equilibrium constant expression for this reaction: 2H+(aq)+CO−23(aq) → H2CO3(aq)
MrRissso [65]

Answer:

Equilibrium constant expression for \rm 2\; H^{+}\, (aq) + {CO_3}^{2-}\, (aq) \rightleftharpoons H_2CO_3\, (aq):

\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \approx \frac{[\mathrm{H_2CO_3}]}{\left[\mathrm{H^{+}\, (aq)}\right]^{2} \, \left[\mathrm{CO_3}^{2-}\right]}.

Where

  • a_{\mathrm{H_2CO_3}}, a_{\mathrm{H^{+}}}, and a_{\mathrm{CO_3}^{2-}} denote the activities of the three species, and
  • [\mathrm{H_2CO_3}], \left[\mathrm{H^{+}}\right], and \left[\mathrm{CO_3}^{2-}\right] denote the concentrations of the three species.

Explanation:

<h3>Equilibrium Constant Expression</h3>

The equilibrium constant expression of a (reversible) reaction takes the form a fraction.

Multiply the activity of each product of this reaction to get the numerator.\rm H_2CO_3\; (aq) is the only product of this reaction. Besides, its coefficient in the balanced reaction is one. Therefore, the numerator would simply be \left(a_{\mathrm{H_2CO_3\, (aq)}}\right).

Similarly, multiply the activity of each reactant of this reaction to obtain the denominator. Note the coefficient "2" on the product side of this reaction. \rm 2\; H^{+}\, (aq) + {CO_3}^{2-}\, (aq) is equivalent to \rm H^{+}\, (aq) + H^{+}\, (aq) + {CO_3}^{2-}\, (aq). The species \rm H^{+}\, (aq) appeared twice among the reactants. Therefore, its activity should also appear twice in the denominator:

\left(a_{\mathrm{H^{+}}}\right)\cdot \left(a_{\mathrm{H^{+}}}\right)\cdot \, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}})\right = \left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}})\right.

That's where the exponent "2" in this equilibrium constant expression came from.

Combine these two parts to obtain the equilibrium constant expression:

\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \quad\begin{matrix}\leftarrow \text{from products} \\[0.5em] \leftarrow \text{from reactants}\end{matrix}.

<h3 /><h3>Equilibrium Constant of Concentration</h3>

In dilute solutions, the equilibrium constant expression can be approximated with the concentrations of the aqueous "(\rm aq)" species. Note that all the three species here are indeed aqueous. Hence, this equilibrium constant expression can be approximated as:

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