Answer:
48.32 g of anhydrous MnSO4.
Explanation:
Equation of dehydration reaction:
MnSO4 •4H2O --> MnSO4 + 4H2O
Molar mass = 55 + 32 + (4*16) + 4((1*2) + 16)
= 223 g/mol
Mass of MnSO4 • 4H2O = 71.6 g
Number of moles = mass/molar mass
= 71.6/223
= 0.32 mol.
By stoichiometry, since 1 mole of MnSO4 •4H2O is dehydrated to give 1 mole of anhydrous MnSO4
Number of moles of MnSO4 = 0.32 mol.
Molar mass = 55 + 32 + (4*16)
= 151 g/mol.
Mass = 151 * 0.32
= 48.32 g of anhydrous MnSO4.
Answer:
The structures are shown in the figure.
Explanation:
The primary hydrogens are those which are attached to primary carbon.
Primary carbons are the carbons which are attached to only one carbon.
Primary carbons is bonded to three hydrogens.
In order to draw such structure we will draw structures which will have carbon with three hydrogens or no hydrogens (quaternary)
The structures are shown in the figure with clear marking.
Answer:
Rank in increasing order of effective nuclear charge:
Explanation:
This explains the meaning of effective nuclear charge, Zeff, how to determine it, and the calculations for a valence electron of each of the five given elements: F, Li, Be, B, and N.
<u>1) Effective nuclear charge definitions</u>
- While the total positive charge of the atom nucleus (Z) is equal to the number of protons, the electrons farther away from the nucleus experience an effective nuclear charge (Zeff) less than the total nuclear charge, due to the fact that electrons in between the nucleus and the outer electrons partially cancel the atraction from the nucleus.
- Such effect on on a valence electron is estimated as the atomic number less the number of electrons closer to the nucleus than the electron whose effective nuclear charge is being determined: Zeff = Z - S.
<u><em>2) Z eff for a F valence electron:</em></u>
- F's atomic number: Z = 9
- Total number of electrons: 9 (same numer of protons)
- Period: 17 (search in the periodic table or do the electron configuration)
- Number of valence electrons: 7 (equal to the last digit of the period's number)
- Number of electrons closer to the nucleus than a valence electron: S = 9 - 7 = 2
- Zeff = Z - S = 9 - 2 = 7
<u><em>3) Z eff for a Li valence eletron:</em></u>
- Li's atomic number: Z = 3
- Total number of electrons: 3 (same number of protons)
- Period: 1 (search on the periodic table or do the electron configuration)
- Number of valence electrons: 1 (equal to the last digit of the period's number)
- Number of electrons closer to the nucleus than a valence electron: S = 3 - 1 = 2
- Z eff = Z - S = 3 - 2 = 1.
<em>4) Z eff for a Be valence eletron:</em>
- Be's atomic number: Z = 4
- Total number of electrons: 4 (same number of protons)
- Period: 2 (search on the periodic table or do the electron configuration)
- Number of valence electrons: 2 (equal to the last digit of the period's number)
- Number of electrons closer to the nucleus than a valence electron: S = 4 - 2 = 2
- Z eff = Z - S = 4 - 2 = 2
<u><em>5) Z eff for a B valence eletron:</em></u>
- B's atomic number: Z = 5
- Total number of electrons: 5 (same number of protons)
- Period: 13 (search on the periodic table or do the electron configuration)
- Number of valence electrons: 3 (equal to the last digit of the period's number)
- Number of electrons closer to the nucleus than a valence electron: S = 5 - 3 = 2
- Z eff = Z - S = 5 - 2 = 3
<u><em>6) Z eff for a N valence eletron:</em></u>
- N's atomic number: Z = 7
- Total number of electrons: 7 (same number of protons)
- Period: 15 (search on the periodic table or do the electron configuration)
- Number of valence electrons: 5 (equal to the last digit of the period's number)
- Number of electrons closer to the nucleus than a valence electron: S = 7 - 5 = 2
- Z eff = Z - S = 7 - 2 = 5
<u><em>7) Summary (order):</em></u>
Atom Zeff for a valence electron
- <u>Conclusion</u>: the order is Li < Be < B < N < F
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