Answer:
A Broad View of Concept Modeling
Establishing Key Relationships
Levels of Concept Modeling
Explanation:
Nitrogen (N2) and hydrogen (H2) gases react to form ammonia, which requires -99.4 J/K of standard entropy (ΔS°).
What is standard entropy?
The difference between the total standard entropies of the reaction mixture and the summation of the standard entropies of the outputs is the standard entropy change. Each entropy in the balanced equation needs to be compounded by its coefficient, as shown by the letter "n."
Calculation:
Balancing the given reaction following-
1/2 N₂(g) + 3/2 H₂ (g)→ NH₃ (g)
ΔS° = [1 mol x S° (NH₃)g] - [1/2 mol x S° (N₂)g] - [3/2 mol x S°(H₂)g]
Here S° = standard entropy of the system
Insert into the aforementioned equation all the typical entropy values found in the literature:
ΔS° = [1 mol x 192.45 J/mol.K] - [1/2 mol x 191.61 J/mol.K] - [3/2 mol x 130.684 J/mol.K]
⇒ΔS° = - 99.4 J/K
Therefore, the standard entropy, ΔS° is -99.4 J/K.
Learn more about standard entropy here:
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Answer:
15.0 L
Explanation:
To find the volume, you need to use the Ideal Gas Law:
PV = nRT
In this equation,
-----> P = pressure (mmHg)
-----> V = volume (L)
-----> n = moles
-----> R = Ideal Gas constant (62.36 L*mmHg/mol*K)
-----> T = temperature (K)
To calculate the volume, you need to (1) convert grams C₄H₁₀ to moles (via the molar mass), then (2) convert the temperature from Celsius to Kelvin, and then (3) calculate the volume (via the Ideal Gas Law).
Molar Mass (C₄H₁₀): 4(12.011 g/mol) + 10(1.008 g/mol)
Molar Mass (C₄H₁₀): 58.124 g/mol
32 grams C₄H₁₀ 1 moles
------------------------- x ----------------------- = 0.551 moles C₄H₁₀
58.124 grams
P = 728 mmHg R = 62.36 L*mmHg/mol*K
V = ? L T = 45.0 °C + 273.15 = 318.15 K
n = 0.551 moles
PV = nRT
(728 mmHg)V = (0.551 moles)(62.36 L*mmHg/mol*K)(318.15 K)
(728 mmHg)V = 10922.7632
V = 15.0 L
