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3 years ago

What’s crystallisation?

1 answer:

8 0

Crystallisation is the process of atoms or molecules arranging into a well-defined, rigid crystal lattice in order to minimize their energetic state.

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Ethanol (C2H5OH) melts a - 144 oC and boils at 78 °C. The enthalpy of fusion of ethanol is 5.02 kj/mol, and its enthalpy of vapo

hammer [34]

Answer:

For a: The total heat required is 36621.5 J

For b: The total heat required is 58944.5 J

Explanation:

For a:

To calculate the heat required at different temperature, we use the equation:

$q=mc\Delta T$ .........(1)

where,

q = heat absorbed

m = mass of substance

$c$ = specific heat capacity of substance

$\Delta T$ = change in temperature

To calculate the amount of heat required at same temperature, we use the equation:

$q=m\times \Delta H$ ........(2)

where,

q = heat absorbed

m = mass of substance

$\Delta H$ = enthalpy of the reaction

The processes involved in the given problem are:

$1.)C_2H_5OH(l)(35^oC)\rightarrow C_2H_5OH(l)(78^oC)\\2.)C_2H_5OH(l)(78^oC)\rightarrow C_2H_5OH(g)(78^oC)$

For process 1:

We are given:

Change in temperature remains the same.

$m=42.0g\\c_l=2.3J/g.K\\T_2=78^oC\\T_1=35^oC\\\Delta T=[T_2-T_1]=[78-35]^oC=43^oC=43K$

Putting values in equation 1, we get:

$q_1=42.0g\times 2.3J/g.K\times 43K\\\\q_1=4153.8J$

For process 2:

We are given:

Conversion factor: 1 kJ = 1000 J

Molar mass of ethanol = 46 g/mol

$m=42.0g\\\Delta H_{vap}=38.56kJ/mol=\frac{35.56kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=773.04J/g$

Putting values in equation 2, we get:

$q_2=42.0g\times 773.04J/g\\\\q_2=32467.7J$

Total heat required = $[q_1+q_2]$

Total heat required = $[4153.8J+32467.7J]=36621.5J$

Hence, the total heat required is 36621.5 J

For b:

The processes involved in the given problem are:

$1.)C_2H_5OH(s)(-155^oC)\rightarrow C_2H_5OH(s)(-144^oC)\\2.)C_2H_5OH(s)(-144^oC)\rightarrow C_2H_5OH(l)(-144^oC)\\3.)C_2H_5OH(l)(-144^oC)\rightarrow C_2H_5OH(l)(78^oC)\\4.)C_2H_5OH(l)(78^oC)\rightarrow C_2H_5OH(g)(78^oC)$

For process 1:

We are given:

Change in temperature remains the same.

$m=42.0g\\c_s=0.97J/g.K\\T_2=-144^oC\\T_1=-155^oC\\\Delta T=[T_2-T_1]=[-144-(-155)]^oC=11^oC=11K$

Putting values in equation 1, we get:

$q_1=42.0g\times 0.97J/g.K\times 11K\\\\q_1=448.14J$

For process 2:

We are given:

$m=42.0g\\\Delta H_{fusion}=5.02kJ/mol=\frac{5.02kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=109.13J/g$

Putting values in equation 2, we get:

$q_2=42.0g\times 109.13J/g\\\\q_2=4583.5J$

For process 3:

We are given:

Change in temperature remains the same.

$m=42.0g\\c_l=2.3J/g.K\\T_2=78^oC\\T_1=-144^oC\\\Delta T=[T_2-T_1]=[78-(-144)]^oC=222^oC=222K$

Putting values in equation 1, we get:

$q_3=42.0g\times 2.3J/g.K\times 222K\\\\q_3=21445.2J$

For process 4:

We are given:

$m=42.0g\\\Delta H_{vap}=38.56kJ/mol=\frac{38.56kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=773.04J/g$

Putting values in equation 2, we get:

$q_4=42.0g\times 773.04J/g\\\\q_4=32467.7J$

Total heat required = $[q_1+q_2+q_3+q_4]$

Total heat required = $[448.14+4583.5+21445.2+32467.7]J=58944.5J$

Hence, the total heat required is 58944.5 J

8 0

3 years ago

Most chemical reactions release energy or are exothermic. However, some reactions, such as some decompositions, absorb energy. T

andre [41]

Answer:

C) The products have more energy stored in their chemical bonds.

Explanation:

In such reactions that absorb energy, the products have more energy stored in their chemical bonds.

For endothermic changes, heat is absorbed from the surrounding hence the surrounding becomes colder at the end of the changes.

The heat energy level of the products is higher than that of the reactants.

Exothermic reactions releases heat to the surroundings. The sum of heat contents of the products is less than that of the hat contents of the reactants.
Examples of such processes are burning and dissolution.

6 0

3 years ago

Which element has properties similar to neon?

Alex777 [14]

Answer:

B. Argon has similar properties to neon.

Explanation:

hope it helps u.

6 0

3 years ago

When you mix copper sulphate solution and steel wool, what is the chemical property that can be observed.

bazaltina [42]

Answer:

Explanation:

depending on the activity series there will probably be a single replacement reaction possibly heat or color change and the copper precipitate out of solution

6 0

3 years ago

Please Help I need an explanation on how to do this

nydimaria [60]

Balanced equation(That should be NaClO_3)

$\\ \rm\Rrightarrow Cl_2+2NaOH\longrightarrow NaCl+NaClO_3+H_2O$

Remember that it's a ionic equation not general equation

We have to balance it accordingly

5 0

2 years ago

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