1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
andreyandreev [35.5K]
3 years ago
13

Ethanol (C2H5OH) melts a - 144 oC and boils at 78 °C. The enthalpy of fusion of ethanol is 5.02 kj/mol, and its enthalpy of vapo

rization is 38.56 kj/mol. The specific heats of solid and liquid ethanol are 0.97j/g - k and 2.3 j/g - K, respectively.
(a) How much heat is required to convert 42.0 g of ethanol at 35 °C to the vapor phase at 78 °C?

(b) How much heat is required to convert the same amount of ethanol at - 155 oC to the vapor phase at 78 °C?
Chemistry
1 answer:
hammer [34]3 years ago
8 0

<u>Answer:</u>

<u>For a:</u> The total heat required is 36621.5 J

<u>For b:</u> The total heat required is 58944.5 J

<u>Explanation:</u>

  • <u>For a:</u>

To calculate the heat required at different temperature, we use the equation:

q=mc\Delta T         .........(1)

where,

q = heat absorbed

m = mass of substance

c = specific heat capacity of substance

\Delta T = change in temperature

To calculate the amount of heat required at same temperature, we use the equation:

q=m\times \Delta H      ........(2)

where,

q = heat absorbed

m = mass of substance

\Delta H = enthalpy of the reaction

The processes involved in the given problem are:

1.)C_2H_5OH(l)(35^oC)\rightarrow C_2H_5OH(l)(78^oC)\\2.)C_2H_5OH(l)(78^oC)\rightarrow C_2H_5OH(g)(78^oC)

  • <u>For process 1:</u>

We are given:

Change in temperature remains the same.

m=42.0g\\c_l=2.3J/g.K\\T_2=78^oC\\T_1=35^oC\\\Delta T=[T_2-T_1]=[78-35]^oC=43^oC=43K

Putting values in equation 1, we get:

q_1=42.0g\times 2.3J/g.K\times 43K\\\\q_1=4153.8J

  • <u>For process 2:</u>

We are given:

Conversion factor: 1 kJ = 1000 J

Molar mass of ethanol = 46 g/mol

m=42.0g\\\Delta H_{vap}=38.56kJ/mol=\frac{35.56kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=773.04J/g

Putting values in equation 2, we get:

q_2=42.0g\times 773.04J/g\\\\q_2=32467.7J

Total heat required = [q_1+q_2]

Total heat required = [4153.8J+32467.7J]=36621.5J

Hence, the total heat required is 36621.5 J

  • <u>For b:</u>

The processes involved in the given problem are:  

1.)C_2H_5OH(s)(-155^oC)\rightarrow C_2H_5OH(s)(-144^oC)\\2.)C_2H_5OH(s)(-144^oC)\rightarrow C_2H_5OH(l)(-144^oC)\\3.)C_2H_5OH(l)(-144^oC)\rightarrow C_2H_5OH(l)(78^oC)\\4.)C_2H_5OH(l)(78^oC)\rightarrow C_2H_5OH(g)(78^oC)

  • <u>For process 1:</u>

We are given:

Change in temperature remains the same.

m=42.0g\\c_s=0.97J/g.K\\T_2=-144^oC\\T_1=-155^oC\\\Delta T=[T_2-T_1]=[-144-(-155)]^oC=11^oC=11K

Putting values in equation 1, we get:

q_1=42.0g\times 0.97J/g.K\times 11K\\\\q_1=448.14J

  • <u>For process 2:</u>

We are given:

m=42.0g\\\Delta H_{fusion}=5.02kJ/mol=\frac{5.02kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=109.13J/g

Putting values in equation 2, we get:

q_2=42.0g\times 109.13J/g\\\\q_2=4583.5J

  • <u>For process 3:</u>

We are given:

Change in temperature remains the same.

m=42.0g\\c_l=2.3J/g.K\\T_2=78^oC\\T_1=-144^oC\\\Delta T=[T_2-T_1]=[78-(-144)]^oC=222^oC=222K

Putting values in equation 1, we get:

q_3=42.0g\times 2.3J/g.K\times 222K\\\\q_3=21445.2J

  • <u>For process 4:</u>

We are given:

m=42.0g\\\Delta H_{vap}=38.56kJ/mol=\frac{38.56kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=773.04J/g

Putting values in equation 2, we get:

q_4=42.0g\times 773.04J/g\\\\q_4=32467.7J

Total heat required = [q_1+q_2+q_3+q_4]

Total heat required = [448.14+4583.5+21445.2+32467.7]J=58944.5J

Hence, the total heat required is 58944.5 J

You might be interested in
What similarities and difference exist between electrons and neutrons? Consider charge, size, location and number.
Alborosie

<u>Charge:</u>

An electron has a negative charge and a <em>n</em>eutron has a <em>n</em>eutral charge.


<u>Size:</u>

Electrons have a really small mass whereas the neutron has a mass of about 1 amu.


<u>Location:</u>

Neutrons are found in center of an atom, but electrons are around it.


<u>Number:</u>

The number of electrons and neutrons in atom varies.

7 0
3 years ago
CHEMISTRY HELP PLEASE *answer all questions please*
Lerok [7]

Answer:

<u><em>Question 1: </em></u>

A) 0.289 moles.

B) 1.74 x 10²³ atoms.

<u><em>Question 2:</em></u>

A) 0.30 moles.  

B) it contains 0.3 moles of both Na and Cl.

C) it contains 6.023 x 10²³ atoms of both Na and Cl.

<u><em>Question 3:</em></u>

A) The number of moles of sucrose (C₁₂H₂₂O₁₁) ≅ 0.0228 moles.

B) The number of moles of C atoms in sucrose (C₁₂H₂₂O₁₁) = 0.2763 mole of C atoms.

The number of moles of H atoms in sucrose (C₁₂H₂₂O₁₁) = 0.5016 mole of H atoms.

The number of moles of O atoms in sucrose (C₁₂H₂₂O₁₁) = 0.2508 mole of O atoms.

C) The number of C atoms = 1.65 x 10²³ atoms.

The number of H atoms = 3.02 x 10²³ atoms.

The number of O atoms = 1.51 x 10²³ atoms.

Explanation:

<u><em>Question 1:</em></u>

A) The number of moles of Au in 57.01 g sample:

n = mass / molar mass,

mass = 57.01 g and molar mass = 196.966 g/mol e.

The number of moles of Au in the sample = (57.01 g) / (196.966 g/mole) = 0.289 moles.

B) The number of atoms of Au in the sample:

It is known that every mole of a substance contains Avogadro,s number (NA = 6.023 x 10²³) of molecules.

1.0 mole of Au → 6.023 x 10²³ atoms

0.289 mole of Au → ???? atoms

<em>using cross multiplication: </em>

The number of atoms of Au in the sample = (6.023 x 10²³ x 0.289 mole) / (1.0 mole) = 1.74 x 10²³ atoms.


<u><em>Question 2:</em></u>

A) The number of moles of 17.45 g of NaCl:

n = mass / molar mass,

mass = 17.45 g and molar mass = 58.44 g/mole.

The number of moles of NaCl = (17.45 g) / (58.44 g/mole) = 0.298 mole ≅ 0.30 moles.

B) The number of moles of each element in NaCl  

NaCl → Na + Cl

Each mole of NaCl contains one mole of Na and one mole of Cl.

<em><u>using cross multiplication: </u></em>

1.0 mole NaCl → 1.0 mole Na

0.3 mole NaCl → ??? mole Na

The number of moles of Na atoms in NaCl = (1.0 mole Na x 0.3 mole NaCl) / (1.0 mole NaCl) = 0.3 mole of Na atoms.

by the same way; the number of moles of Cl atoms = (1.0 mole Cl x 0.3 mole NaCl) / (1.0 mole NaCl) = 0.3 mole of Cl atoms.

C) The number of atoms of each element in the sample:

It is known that every mole of a substance contains Avogadro,s number (NA = 6.023 x 10²³) of molecules.

1.0 mole of NaCl → 6.023 x 10²³ molecules

0.3 mole of NaCl → ???? molecules

<em><u>using cross multiplication:</u></em>

The number of molecules in 0.3 mole of NaCl = (6.023 x 10²³ x 0.3 mole) / (1.0 mole) = 1.8069 x 10²³ molecules.

Every molecule of NaCl contains one atom of Na and one atom of Cl.

So, it contains 6.023 x 10²³ atoms of both Na and Cl.


<u><em>Question 3:</em></u>

A) The number of moles of 7.801 g of sucrose (C₁₂H₂₂O₁₁):

n = mass / molar mass,

mass = 7.801 g and molar mass = 342.3 g/mole.

The number of moles of sucrose (C₁₂H₂₂O₁₁) = (7.801 g) / (342.3 g/mol) = 0.022789 mol ≅ 0.0228 moles.

B) The number of moles of each element in sucrose (C₁₂H₂₂O₁₁):

C₁₂H₂₂O₁₁ → 12C + 22H + 11O

Each mole of sucrose contains 12 moles of C, 22 moles of H, and 11 moles of O.

  • <em><u>using cross multiplication: </u></em>

1.0 mole of sucrose (C₁₂H₂₂O₁₁) → 12.0 moles C

0.0228 mole of sucrose (C₁₂H₂₂O₁₁) → ??? moles C

The number of moles of C atoms in sucrose (C₁₂H₂₂O₁₁) = (12.0 moles C x 0.0228 moles of sucrose (C₁₂H₂₂O₁₁)) / (1.0 mole sucrose (C₁₂H₂₂O₁₁)) = 0.2763 mole of C atoms.

  • By the same way; the number of moles of H atoms:

1.0 mole of sucrose (C₁₂H₂₂O₁₁) → 22.0 moles H

0.0228 mole of sucrose (C₁₂H₂₂O₁₁) → ??? moles H

The number of moles of H atoms in sucrose (C₁₂H₂₂O₁₁) = (22.0 moles H x 0.0228 moles of sucrose (C₁₂H₂₂O₁₁)) / (1.0 mole sucrose (C₁₂H₂₂O₁₁)) = 0.5016 mole of H atoms.

  • Also; the number of moles of O atoms:

1.0 mole of sucrose (C₁₂H₂₂O₁₁) → 11.0 moles O

0.0228 mole of sucrose (C₁₂H₂₂O₁₁) → ??? moles O

The number of moles of O atoms in sucrose (C₁₂H₂₂O₁₁) = (11.0 moles H x 0.0228 moles of sucrose (C₁₂H₂₂O₁₁)) / (1.0 mole sucrose (C₁₂H₂₂O₁₁)) = 0.2508 mole of O atoms.

C) The number of atoms of each element in the sucrose (C₁₂H₂₂O₁₁) sample:

It is known that every mole of a substance contains Avogadro,s number (NA = 6.023 x 10²³) of molecules.

1.0 mole of sucrose (C₁₂H₂₂O₁₁) → 6.023 x 10²³ molecules

0.0228 mole of sucrose (C₁₂H₂₂O₁₁) → ???? molecules

<em><u>using cross multiplication: </u></em>

The number of molecules in 0.0228 mole of sucrose (C₁₂H₂₂O₁₁) = (6.023 x 10²³ x 0.0228 mole) / (1.0 mole) = 1.273 x 10²² molecules.

Each molecule of sucrose contains 12 atoms of C, 22 atoms of H, and 11 atoms of O.

So, the number of each atom that the sucrose (C₁₂H₂₂O₁₁) sample contains are:

The number of C atoms = (12 x 1.273 x 10²² molecules) = 1.65 x 10²³ atoms.

The number of H atoms = (22 x 1.273 x 10²² molecules) = 3.02 x 10²³ atoms.

The number of O atoms = (11 x 1.273 x 10²² molecules) = 1.51 x 10²³ atoms.

6 0
3 years ago
A student takes a measured volume of 3.00 M HCl to prepare a 50.0 mL sample of 1.80 M HCI. What volume of 3.00 M HCI
frozen [14]

Answer:

30 mL VOLUME OF 3.0 M HCl SHOULD BE USED BY THE STUDENT TO MAKE A 1.80 M IN 50 mL OF HCl.

Explanation:

M1 = 3.00 M

M2 = 1.80 M

V2 = 50 .0 mL = 50 /1000 L = 0.05 L

V1 = unknown

In solving this question, we know that number of moles of a solution is equal to the molar concentration multiplied by the volume. To compare two samples, we equate both number of moles and substitute for the required component.

So we use the equation:

                                  M1 V1 = M2 V2

V1 = M2 V2 / M1

V2 = 1.80 * 0.05 / 3.0

V2 = 0.09 /3.0

V2 = 0.03 L or 30 mL

To prepare the sample of 1.80 M HCl in 50.0 mL from a 3.0 M HCl, 30 mL volume should be used.

5 0
3 years ago
Ants live on acacia trees in South America. The ants feed on sugars secreted by the trees. The trees provide room for the ants t
Stolb23 [73]
Mutualism! The tree provides a home and food for the ants, while the ants protect the tree :)
8 0
3 years ago
If a decrease in temperature accompanies a reaction, what occurred?
marusya05 [52]
Released my friending
8 0
3 years ago
Read 2 more answers
Other questions:
  • A diatom is a(n) _______ because it has _______.
    8·1 answer
  • A sample of vinegar has a pH of 5, and a sample of rainwater has a pH of 6. Which of the following statements best describes the
    13·2 answers
  • All atoms of an element always have the same number of question 4 options: electrons protons electrons neutrons save
    8·1 answer
  • Which glacial landforms require more than one glacier to form
    15·2 answers
  • How many molecules are there in 79g of Fe2O3? how many atoms is thi
    8·1 answer
  • If an atom has an average atomic mass of 238.03 amu and has 92 protons, how many electrons does it have?
    11·1 answer
  • The Constitution gives which of the following powers to the Vice President?
    11·2 answers
  • The number 89.667 rounded off to three significant figures is
    11·1 answer
  • Q3. A new pill (Wardine) has been created that reduces the side effects of the common cold! The
    12·1 answer
  • The actual density of iron is 7.874 g/mL. In a laboratory investigation, Jason finds the density of a piece of iron to be 7.921
    5·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!