Theoretically, we expect "6" to show up once every 6 rolls assuming we have a fair die. So about 1/6 = 0.17 = 17% of the time.
The table on the other hand shows "6" showing up 14 times out of 100 to get an experimental probability of 14/100 = 0.14 = 14% which is 3 percentage points less than the theoretical estimate.
