Using Gay-Lussac's law you get the equation and converting celcius you get the final equation of . After dividing 85.5 by 27+273(300) you get 0.285 and then you multiply 0.285 by 127+273 (400). You finally get 114 kPa
The difference is due to the degree of dissociation of the substances. HCl dissociates completely into ions when added to water, while this is not the case for HC₂H₃O₂; therefore, HCl has a lower pH.