To know the acidity of a
solution, we calculate the pH value. The formula for pH is given as:
<span>pH = - log [H+] where H+ must be in Molar</span>
We are given that H+ = 3.25 × 10-2 M
Therefore the pH is:
pH = - log [3.25 × 10-2]
pH = 1.488
Since pH is way below 7, therefore the solution
is acidic.
To find for the OH- concentration, we must
remember that the product of H+ and OH- is equivalent to 10^-14. Therefore,
[H+]*[OH-] = 10^-14 <span>
</span>[OH-] = 10^-14 / [H+]
[OH-] = 10^-14 / 3.25 × 10-2
[OH-] = 3.08 × 10-13 M
Answers:
Acidic
[OH-] = 3.08 <span>× 10-13 M</span>
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The Change in Gibb's free energy, ΔG for the reaction at 298K is; -56.92KJ.
<h3>Gibb's free energy of reactions</h3>
It follows from the Gibb's free energy formula as expressed in terms of Enthalpy and Entropy that;
On this note, it follows that;
Hence, the Gibb's free energy for the reaction is;
- ΔG = 14.6 - 71.52
- ΔG = -56.92KJ
Remarks: The question requires that we determine the Gibb's free energy for the reaction at 298K.
Read more on Gibb's free energy;
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Aniline can be produced from nitro-benzene by reduction. When nitro-benzene reacts with tin (Sn) + hydrochloride acid (HCl) then aniline is produced. The Sn + HCl forms free hydrogen ions which converts the nitro group of the benzene ring to amine group, which is aniline. In place of Sn + HCl. One can use palladium (Pd) hydrogen mixture in presence of ethanol (EtOH). There produces a side product in this reaction which is cyclohexyl amine. The reaction can be shown as.