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castortr0y [4]
1 year ago
6

Br2(g) cl2(g)⇌2brcl(g) δh∘f for brcl(g) is 14. 6 kj/mol. Δs∘f for brcl(g) is 240. 0 j/mol

Chemistry
2 answers:
adelina 88 [10]1 year ago
6 0

The Gibbs free energy for the reaction Br²(g) Cl²(g)⇌2BrCl(g) is -56.92 KJ.

<h3>What is Gibbs Free energy?</h3>

It's the total work done in a closed thermodynamic system.

By the formula of Gibbs free energy

\rm  \Delta G =   \Delta H - T  \Delta S

The H is 14.6 KJ/mol

The change in temperature is 0.24

Putting the values in the equation

\Delta G = 14.6 - (298  \times 0.24)\\\\ \Delta G = 14.6 - 71.52\\\\ \Delta G = -56.92KJ

Thus, the Gibbs free energy for the reaction is -56.92 KJ

Learn more about Gibbs Free energy

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max2010maxim [7]1 year ago
5 0

The Change in Gibb's free energy, ΔG for the reaction at 298K is; -56.92KJ.

<h3>Gibb's free energy of reactions</h3>

It follows from the Gibb's free energy formula as expressed in terms of Enthalpy and Entropy that;

  • ΔG = ΔH - TΔS

On this note, it follows that;

  • ΔG = 14.6 - (298× 0.24)

Hence, the Gibb's free energy for the reaction is;

  • ΔG = 14.6 - 71.52
  • ΔG = -56.92KJ

Remarks: The question requires that we determine the Gibb's free energy for the reaction at 298K.

Read more on Gibb's free energy;

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Consider the reaction: CaCO3(s) à CaO(s) + CO2(g)
Vsevolod [243]

Answer:

131.5 kJ

Explanation:

Let's consider the following reaction.

CaCO₃(s) → CaO(s) + CO₂(g)

First, we will calculate the standard enthalpy of the reaction (ΔH°).

ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g) ) - 1 mol × ΔH°f(CaCO₃(s) )

ΔH° = 1 mol × (-634.9 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1207.6 kJ/mol)

ΔH° = 179.2 kJ

Then, we calculate the standard entropy of the reaction (ΔS°).

ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g) ) - 1 mol × S°(CaCO₃(s) )

ΔS° = 1 mol × (38.1 J/mol.K) + 1 mol × (213.8 J/mol.K) - 1 mol × (91.7 J/mol.K)

ΔS° = 160.2 J/K = 0.1602 kJ/K

Finally, we calculate the standard Gibbs free energy of the reaction at T = 25°C = 298 K.

ΔG° = ΔH° - T × ΔS°

ΔG° = 179.2 kJ - 298 K × 0.1602 kJ/K

ΔG° = 131.5 kJ

6 0
3 years ago
Two isotopes of lithium are found in nature Li6 has a mass of 6. 02u and Li7 has a mass of 7.02u . Use the atomic weight of lith
alexandr402 [8]

The isotope that is more abundant, given the data is isotope Li7

<h3>Assumption</h3>
  • Let Li6 be isotope A
  • Let Li7 be isotope B

<h3>How to determine whiche isotope is more abundant</h3>
  • Molar mass of isotope A (Li6) = 6.02 u
  • Molar mass of isotope B (Li7) = 7.02 u
  • Atomic mass of lithium = 6.94 u
  • Abundance of A = A%
  • Abundance of B = (100 - A)%

Atomic mass = [(mass of A × A%) / 100] + [(mass of B × B%) / 100]

6.94 = [(6.02 × A%) / 100] + [(7.02 × (100 - A)) / 100]

6.94 = [6.02A% / 100] + [702 - 7.02A% / 100]

6.94 = [6.02A% + 702 - 7.02A%] / 100

Cross multiply

6.02A% + 702 - 7.02A% = 6.94 × 100

6.02A% + 702 - 7.02A% = 694

Collect like terms

6.02A% - 7.02A% = 694 - 702

-A% = -8

A% = 8%

Thus,

Abundance of B = (100 - A)%

Abundance of B = (100 - 8)%

Abundance of B = 92%

SUMMARY

  • Abundance of A (Li6) = 8%
  • Abundance of B (Li7) = 92%

From the above, isotope Li7 is more abundant.

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