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2 years ago

Calculate the pressure (in kpa) of 1.5 mole of helium gas at 354 k when it occupies a volume of 16.5l.

Chemistry

1 answer:

3241004551 [841]2 years ago

8 0

Answer:

267.57 kPa

Explanation:

Ideal gas law:

PV = n RT R = 8.314462 L-kPa/K-mol

P (16.5) = 1.5 (8.314462)(354) P = 267.57 kPa

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In acidic aqueous solution, the purple complex ion Co(NH3)5Br2+ undergoes a slow reaction in which the bromide ion is replaced b

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Answer:

A) 0.065 M is its molarity after a reaction time of 19.0 hour.

B) In 52 hours $[Co(NH_3)5Br]^{2+}$ will react 69% of its initial concentration.

Explanation:

$Co(NH_3)_5(H_2O)_3+[Co(NH_3)5Br]^{2+}(Purple)(aq)+H_2O(l)\rightarrow [Co(NH_3)_5(H_2O)]^{3+}(Pinkish-orange)(aq)+Br^-(aq)$

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Initial concentration of $[Co(NH_3)5Br]^{2+}$ = $[A_o]=0.100 M$

a) Final concentration of $[Co(NH_3)5Br]^{2+}$ after 19.0 hours= $[A]$

t = 19.0 hour = 19.0 × 3600 seconds ( 1 hour = 3600 seconds)

Rate constant of the reaction = k = $6.3\times 10^{-6} s^{-1}$

The integrated law of first order kinetic is given as:

$[A]=[A_o]\times e^{-kt}$

$[A]=0.100 M\times e^{-6.3\times 10^{-6} s^{-1}\times 19.0\times 3600 s}$

$[A]=0.065 M$

0.065 M is its molarity after a reaction time of 19.0 h.

Initial concentration of $[Co(NH_3)5Br]^{2+}$ = $[A_o]=x$

Final concentration of $[Co(NH_3)5Br]^{2+}$ after t = $[A]=(100\%-69\%) x=31\%x=0.31x$

Rate constant of the reaction = k = $6.3\times 10^{-6} s^{-1}$

The integrated law of first order kinetic is given as:

$[A]=[A_o]\times e^{-kt}$

$0.31x=x\times e^{-6.3\times 10^{-6} s^{-1}\t}$

t = 185,902.06 s = $\frac{185,902.06 }{3600} hour = 51.64 hours$ ≈ 52 hours

In 52 hours $[Co(NH_3)5Br]^{2+}$ will react 69% of its initial concentration.

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