A sample of gas exerts a pressure of 16 atm at a temperature of 340 K. What is the pressure of the gas in atm if the temperature
1 answer:
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Answer:
Explanation:
If we look at the structure of 1-Bromopropane; we will see that it is a derivative of alkane family by the the substitution of an alkyl group. The position of the Bromine in the propane is 1, making 1-Bromopropane a primary alkyl-halide.
Primary alkyl - halide undergo SN2 mechanism. This nucleophilic reaction needs to be a strong alkyl halide , such as 1-Bromopropane used otherwise it will result to a reactive mechanism if a weak electrophile is used.
However, the critical and the main objective here is to Draw the major substitution product if the reaction proceeds in good yield. If no reaction is expected or yields will be poor, draw the starting material in the box. If a charged product is formed, be sure to draw the counterion.
The attached diagrams portraying this notions is shown in the attached file below.
Answer:
The [SO₃²⁻]
Explanation:
From the first dissociation of sulfurous acid we have:
H₂SO₃(aq) ⇄ H⁺(aq) + HSO₃⁻(aq)
At equilibrium: 0.50M - x x x
The equilibrium constant (Ka₁) is:
With Ka₁= 1.5x10⁻² and solving the quadratic equation, we get the following HSO₃⁻ and H⁺ concentrations:
Similarly, from the second dissociation of sulfurous acid we have:
HSO₃⁻(aq) ⇄ H⁺(aq) + SO₃²⁻(aq)
At equilibrium: 7.94x10⁻²M - x x x
The equilibrium constant (Ka₂) is:
Using Ka₂= 6.3x10⁻⁸ and solving the quadratic equation, we get the following SO₃⁻ and H⁺ concentrations:
Therefore, the final concentrations are:
[H₂SO₃] = 0.5M - 7.94x10⁻²M = 0.42M
[HSO₃⁻] = 7.94x10⁻²M - 7.07x10⁻⁵M = 7.93x10⁻²M
[SO₃²⁻] = 7.07x10⁻⁵M
[H⁺] = 7.94x10⁻²M + 7.07x10⁻⁵M = 7.95x10⁻²M
So, the lowest concentration at equilibrium is [SO₃²⁻] = 7.07x10⁻⁵M.
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