Answer:
C
Explanation:
A negative deltaH means that the reaction has to give up heat in order to happen. You have to treat deltaH as a reactant. So the question is do you need to add heat to the reactants to make the products. If you do, deltaH is plus.
Heat is required to make a solid go to a gas. deltaH is plus. A is not the answer.
A lot of heat is required for B (something like 400 Kj / mole. Like A, deltaH is plus and B is not the answer.
C: The liquid has to give up heat in order for the this reaction to take place. C is the answer.
D requires heat. It is not the answer.
since both the jars are kept at the same temperature the vapor pressure will be same in both the cases.
Answer: The activation energy Ea for this reaction is 22689.8 J/mol
Explanation:
According to Arrhenius equation with change in temperature, the formula is as follows.
![ln \frac{k_{2}}{k_{1}} = \frac{-E_{a}}{R}[\frac{1}{T_{2}} - \frac{1}{T_{1}}]](https://tex.z-dn.net/?f=ln%20%5Cfrac%7Bk_%7B2%7D%7D%7Bk_%7B1%7D%7D%20%3D%20%5Cfrac%7B-E_%7Ba%7D%7D%7BR%7D%5B%5Cfrac%7B1%7D%7BT_%7B2%7D%7D%20-%20%5Cfrac%7B1%7D%7BT_%7B1%7D%7D%5D)
= rate constant at temperature
= ![2.3\times 10^8](https://tex.z-dn.net/?f=2.3%5Ctimes%2010%5E8)
= rate constant at temperature
=
= activation energy = ?
R= gas constant = 8.314 J/kmol
= temperature = ![280.0^0C=(273+280)=553K](https://tex.z-dn.net/?f=280.0%5E0C%3D%28273%2B280%29%3D553K)
= temperature = ![376.0^0C=(273+376)=649K](https://tex.z-dn.net/?f=376.0%5E0C%3D%28273%2B376%29%3D649K)
Putting in the values ::
![ln \frac{4.8\times 10^8}{2.3\times 10^8} = \frac{-E_{a}}{8.314}[\frac{1}{649} - \frac{1}{553}]](https://tex.z-dn.net/?f=ln%20%5Cfrac%7B4.8%5Ctimes%2010%5E8%7D%7B2.3%5Ctimes%2010%5E8%7D%20%3D%20%5Cfrac%7B-E_%7Ba%7D%7D%7B8.314%7D%5B%5Cfrac%7B1%7D%7B649%7D%20-%20%5Cfrac%7B1%7D%7B553%7D%5D)
![E_a=22689.8J/mol](https://tex.z-dn.net/?f=E_a%3D22689.8J%2Fmol)
The activation energy Ea for this reaction is 22689.8 J/mol