Answer is: Ksp for calcium sulfate is 2.36·10⁻⁴.
Balanced chemical reaction (dissociation):
CaSO₄(s) → Ba²⁺(aq) + SO₄²⁻(aq).
m(CaSO₄) = 0.209 g.
n(CaSO₄) = m(CaSO₄) ÷ M(CaSO₄).
n(CaSO₄) = 0.209 g ÷ 136.14 g/mol.
n(CaSO₄) = 0.00153 mol.
s(CaSO₄) = n(CaSO₄) ÷ V(CaSO₄).
s(CaSO₄) = 0.00153 mol ÷ 0.1 L = 0.0153 M.
Ksp = [Ca²⁺] · [SO₄²⁻].
[Ca²⁺] = [SO₄²⁻] = s(CaSO₄).
Ksp = (0.0153 M)² = 2.36·10⁻⁴.
Answer : The correct answer is 1) AlCl₃ - CH₃Cl 2) HNO₃ -H₂SO₄ at room temperature 3) Fuming HNO₃ -H₂SO₄ at 90-100 ⁰ C heat .
I think this reaction is forming 2,4,6- trinitrotoluene from benzene, since the product is not mentioned. Following are the steps to convert Benzene to 2,4,6 trinitrotoluene .
Step 1: Conversion of Benzene to Toluene .
Benzene can be converted to toluene by Friedel Craft Alkylation of benzene . In this reaction reagent AlCl₃ and Ch3Cl is used . Electrophile CH³⁺ is produced which attached on carbon of benzene and formation of Toluene and HCl occur.

Step 2 : Conversion of Toluene to dinitrotoluene.
Dinitritoluene is prepared from toluene by Nitration . This reaction uses Electrophilic substitution mechanism . The reagents used are HNO₃ and H₂SO₄ at room temperature . These reagents produces NO₂⁺ ( nitronium ion ), a electrophile which attacks on C2 and C4 Carbon atoms of Toluene.
Toluene 
Step 3) Conversion of Dinitro toluene to trinitrotoluene.
This reaction is extended nitration of toluene . Further nitration is done in extreme condition . The temperature of reaction is increased to 90- 100 ⁰ C . Due to which there is more production of NO²⁺ ion occurs from HNO₃ -H₂SO₄ and they attack on C6 carbon atom of dinitrotoluene which forms 2,4,6- trinitrotoluene.
Dinitrotoluene 
So over all reaction uses three reagents in order :

Theoretical yield 550 kg - 100%
Actual yield 480 kg - x%
x= 480*100/550 ≈ 87.3 %
Percentage yield ≈ 87.3 %.
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