Which sample contains more atoms: 3.89 g of nickel or 6.61 g of silver? Defend your answer.
1 answer:
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Answer:
See explanation below
Explanation:
In this case we have reaction of addition. In this case a diene reacting with an acid as HBr. This reaction is known as Hydrohalogenation, and, as we have a diene, this kind of reaction can be done as 1,4 addition. Which means that the reaction will be undergoing with an adition in the carbon 1, and carbon 4.
At room temperature we can expect that this reaction can be done in thermodynamic conditions, Now, as the problem states that is forming 4 products, we can expect products of a 1,2 addition too. This product can be formed if the reaction is taking place in the most stable carbocation, and then, by resonance, we can expect the 1,4 product too.
Now, the HBr can be attacked by the double bond of the first position, giving two possible products or by the double bond of the third position giving the other two products. These products are all possible, obviously the most stable will be the major of all of them, but the other three are perfectly possible. One product is formed without doing much, and the other by resonance. Same happens with the other double bond.
In the picture below, you have the mechanism for all the 4 products.
Hope this helps
Answer:
See explanation
Explanation:
The reaction that we are considering here is quite a knotty reaction. It is difficult to decide if the mechanism is actually E1 or E2 since both are equally probable based on the mass of scientific evidence regarding this reaction. However, we can easily assume that the methylenecyclohexane was formed by an E1 mechanism.
Looking at the products, one could convincingly assert that the reaction leading to the formation of the two main products proceeds via an E1 mechanism with the formation of a carbocation intermediate as has been shown in mechanism attached to this answer. Possible rearrangement of the carbocation yields the 3-methylcyclohexene product.
