Answer:
Chemical reaction involves the breaking of bonds in the reactants and formation of bonds in the products. ... If a reaction is exothermic, more energy is released when the bonds of the products are formed than it takes to break the bonds of the reactants. This is the reason for temperature change during a reaction.
Explanation:
Here are just a few everyday demonstrations that temperature changes the rate of chemical reaction: Cookies bake faster at higher temperatures. Bread dough rises more quickly in a warm place than in a cool one.
A free-radical substitution reaction is likely to be responsible for the observations. The reaction mechanism of a reaction like this can be grouped into three phases:
- Initiation; the "light" on the mixture deliver sufficient amount of energy such that the halogen molecules undergo homologous fission. It typically takes ultraviolet radiation to initiate fissions of the bonds.
- Propagation; free radicals react with molecules to produce new free radicals and molecules.
- Termination; two free radicals combine and form covalent bonds to produce stable molecules. Note that it is possible for two carbon-containing free-radicals to combine, leading to the production of trace amounts of long carbon chains in the product.
Initiation
where the big black dot indicates unpaired electrons attached to the atom.
Propagation
Termination
According to Raoult's low:
We will use this formula: Vp(Solution) = mole fraction of solvent * Vp(solvent)
∴ mole fraction of solvent = Vp(Solu) / Vp (Solv)
when we have Vp(solu) = 25.7 torr & Vp(solv) = 31.8 torr
So by substitution:
∴ mole fraction of solvent = 25.7 / 31.8 =0.808
when we assume the moles of solute NaCl = X
and according to the mole fraction of solvent formula:
mole fraction of solvent = moles of solvent / (moles of solvent + moles of solute)
by substitute:
∴ 0.808 = 0.115 / (0.115 + X)
So X (the no.of moles of NaCl) = 0.027 m
N(CH₃OH)=3,62·10²⁴/6·10²³ 1/mol = 6,033 mol
m(CH₃OH) = 6,033 mol · 32 g/mol (molar mass) = 193,06 g.
