Answer:
The volume would be; 136.17 ml
Explanation:
Volume V1 = 150 mL
Temperature T1 = 20°C + 273 = 293 K
Pressure P1 = 758 - 17.54 = 740.46 torr
At STP;
Volume V2 = ?
Pressure P2 = 760 torr
Temperature T2 = 273 K
Using the general gas equation;
P1V1 / T1 = P2V2 / T2
Making V2 subject of formulae;
V2 = P1V1T2 / T1P2
Inserting the values we have;
V2 = 740.46 * 150 * 273 / 293 * 760
V2 = 136.17 ml
Answer & Explanation:
(a)

reducing agent = Fe²⁺
Oxidizing agent = NO₃⁻
oxidation
Fe²⁺ ⇒ Fe(OH)₃
reduction
NO₃⁻ ⇒ N₂
Oxidation Half Reaction
(<em>redox reactions are balanced by adding appropriate H⁺ and H₂O atoms)</em>
Fe²⁺ ⇒ Fe(OH)₃
Balance O atoms
Fe²⁺ + 3H₂O ⇒ Fe(OH)₃
Balance H atoms
Fe² + 3H₂0 ⇒ Fe(OH)₃ + 3H⁺
balance Charge
Fe² + 3H₂0 ⇒ Fe(OH)₃ + 3H⁺ + e⁻..............(1)
reduction Half Reaction
NO₃⁻ ⇒ N₂
Balance N atoms
2NO₃⁻ ⇒N₂
Balance O atoms by adding appropriate H₂O
2NO₃⁻ ⇒ N₂ + 6H₂O
Balance H atoms
2NO₃⁻ + 12H⁺ ⇒ N₂ + 6H₂O
Balance Charge
2NO₃⁻ + 12H⁺ + 10e⁻⇒ N₂ + 6H₂O.................(2)
Combine Equation (1) and (2)
(1) × 10: 10Fe² + 30H₂0 ⇒ 10Fe(OH)₃ + 30H⁺ + 10e⁻
(2) × 1: 2NO₃⁻ + 12H⁺ + 10e⁻⇒ N₂ + 6H₂O
(1) + (2): 10Fe² + <u><em>30H₂0</em></u> + 2NO₃⁻ + <u><em>12H⁺</em></u> + <u><em>10e⁻</em></u> ⇒10Fe(OH)₃ + <u><em>30H⁺</em></u><u><em> </em></u>+ <em><u>10e⁻</u></em> +
N₂ + <u><em>6H₂O</em></u>
10Fe² + 24H₂0 + 2NO₃⁻ ⇒ 10Fe(OH)₃ + 18H⁺ + N₂
this is the balanced reaction
REDUCTION POTENTIAL
10Fe²⁺(aq) + 10e⁻ ⇒ 10Fe(OH)₃(aq) E°ox = 10(-0.44) = -4.4V
2NO₃⁻(aq) - 2e⁻ ⇌ N₂(g) + 18H⁺ E°red = 2(+0.80) = +1.6
10Fe² + 24H₂0 + 2NO₃⁻ ⇒ 10Fe(OH)₃ + 18H⁺ + N₂ E°cell = -2.8V
E°cell = E°red + E°ox
Answer:
Beginning or Start
Explanation:
Reactions can be followed by measuring changes in concentration, mass and volume of reactants or products. The rate is highest at the start of the reaction because the concentration of reactants is highest at this point.
Hope this helped! :^)