Explanation:
1. Thermochemical equation is balance stoichiometric chemical equation written with the phases of the reactants and products in the brackets along with the enthalpy change of the reaction.
The given correct thermochemical reactions are:
2. Phase change affect the value of the enthalpy change of the thermochemical equation. This is because change in phase is accompanied by change in energy. For example:
In both reaction phase of water is changing with change in energy of enthalpy of reaction.
Answer:
The correct answer is entropy change of the surrounding plus the entropy change of the system must be positive.
Explanation:
The term entropy is a state function.Entropy can be defined as the disorder or randomness of the molecules in a system.
A spontaneous reaction is a type of reaction which deals with the release of free energy.The change of free energy in case of spontaneous reaction is always negative.
According to the second law of thermodynamics a spontaneous reaction will occur in a system if the total entropy of both system and surrounding increases during the reaction.