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1 year ago

A mixture of 0.600 mol of bromine and 1.600 mol of iodine is placed into a rigid 1.000-L container at 350°C.

Chemistry

1 answer:

kaheart [24]1 year ago

4 0

The equilibrium constant of the reaction is 282. Option D

<h3>What is equilibrium constant?</h3>

The term equilibrium constant refers to the number that often depict how much the process is able to turn the reactants in to products. In other words, if the reactants are readily turned into products, then it follows that the equilibrium constant will be large and positive.

Concentration of bromine = 0.600 mol /1.000-L = 0.600 M

Concentration of iodine = 1.600 mol/1.000-L = 1.600M

In this case, we must set up the ICE table as shown;

Br2(g) + I2(g) ↔ 2IBr(g)

I 0.6 1.6 0

C -x -x +2x

E 0.6 - x 1.6 - x 1.190

If 2x = 1.190

x = 1.190/2

x = 0.595

The concentrations at equilibrium are;

[Br2] = 0.6 - 0.595 = 0.005

[I2] = 1.6 - 0.595 = 1.005

Hence;

Kc = [IBr]^2/[Br2] [I2]

Kc = ( 1.190)^2/(0.005) (1.005)

Kc = 282

Learn more about equilibrium constant:brainly.com/question/15118952

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Answer : The initial rate for a reaction will be $3.4\times 10^{-3}Ms^{-1}$

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Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

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Rate law expression for the reaction:

$\text{Rate}=k[A]^a[B]^b[C]^c$

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c = order with respect to C

Expression for rate law for first observation:

$6.0\times 10^{-5}=k(0.20)^a(0.20)^b(0.20)^c$ ....(1)

Expression for rate law for second observation:

$1.8\times 10^{-4}=k(0.20)^a(0.20)^b(0.60)^c$ ....(2)

Expression for rate law for third observation:

$2.4\times 10^{-4}=k(0.40)^a(0.20)^b(0.20)^c$ ....(3)

Expression for rate law for fourth observation:

$2.4\times 10^{-4}=k(0.40)^a(0.40)^b(0.20)^c$ ....(4)

Dividing 1 from 2, we get:

$\frac{1.8\times 10^{-4}}{6.0\times 10^{-5}}=\frac{k(0.20)^a(0.20)^b(0.60)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\3=3^c\\c=1$

Dividing 1 from 3, we get:

$\frac{2.4\times 10^{-4}}{6.0\times 10^{-5}}=\frac{k(0.40)^a(0.20)^b(0.20)^c}{k(0.20)^a(0.20)^b(0.20)^c}\\\\4=2^a\\a=2$

Dividing 3 from 4, we get:

$\frac{2.4\times 10^{-4}}{2.4\times 10^{-4}}=\frac{k(0.40)^a(0.40)^b(0.20)^c}{k(0.40)^a(0.20)^b(0.20)^c}\\\\1=2^b\\b=0$

Thus, the rate law becomes:

$\text{Rate}=k[A]^2[B]^0[C]^1$

Now, calculating the value of 'k' by using any expression.

Putting values in equation 1, we get:

$6.0\times 10^{-5}=k(0.20)^2(0.20)^0(0.20)^1$

$k=7.5\times 10^{-3}M^{-2}s^{-1}$

Now we have to calculate the initial rate for a reaction that starts with 0.75 M of reagent A and 0.90 M of reagents B and C.

$\text{Rate}=k[A]^2[B]^0[C]^1$

$\text{Rate}=(7.5\times 10^{-3})\times (0.75)^2(0.90)^0(0.90)^1$

$\text{Rate}=3.4\times 10^{-3}Ms^{-1}$

Therefore, the initial rate for a reaction will be $3.4\times 10^{-3}Ms^{-1}$

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