The masses of CO and CO2 are 90.55g and 100−90.55=9.45 g respectively.
<h3>Total mass.</h3>
Let the mixture has 100g as total mass.
The number of moles of CO is 2890.55=3.234.
The number of moles of CO2 is 449.45=0.215.
The mole fraction of CO is 3.234+0.2153.234=0.938.
The mole fraction of CO2 is 1−0.938=0.062.
The partial pressure of CO is the product of the mole fraction of CO and the total pressure.
It is 0.938×1=0.938 atm.
The partial pressure of carbon dioxide is 0.062×1=0.042 atm.
The expression for the equilibrium constant is:
Kp=PCO2PCO2=0.062(0.938)2=14.19
Δng=2−1=1
Kc=Kp(RT)−Δn=14.19×(0.0821×1127)−1=0.153.
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