Answer:
The number of moles = 0.06 moles
Explanation:
i) Formula
Number of moles = Mass of the sample ÷ Molar masses of the substances
ii) Number of moles = 10.0 ÷ (137)+(19×2)
= 10.0 ÷ 175
= 0.06 moles
Using the Henderson-Hasselbalch equation on the solution before HCl addition: pH = pKa + log([A-]/[HA]) 8.0 = 7.4 + log([A-]/[HA]); [A-]/[HA] = 4.0. (equation 1) Also, 0.1 L * 1.0 mol/L = 0.1 moles total of the compound. Therefore, [A-] + [HA] = 0.1 (equation 2) Solving the simultaneous equations 1 and 2 gives: A- = 0.08 moles AH = 0.02 moles Adding strong acid reduces A- and increases AH by the same amount. 0.03 L * 1 mol/L = 0.03 moles HCl will be added, soA- = 0.08 - 0.03 = 0.05 moles AH = 0.02 + 0.03 = 0.05 moles Therefore, after HCl addition, [A-]/[HA] = 0.05 / 0.05 = 1.0 Resubstituting into the Henderson-Hasselbalch equation: pH = 7.4 + log(1.0) = 7.4, the final pH.
Answer:
To determine the enthalpy and entropy of dissolving a compound, you need to measure the Ksp at multiple temperatures. Then, plot ln(Ksp) vs. 1/T. The slope of the plotted line relates to the enthalpy (ΔH) of dissolving and the intercept of the plotted line relates to the entropy (ΔS) of dissolving.
Explanation:
Hello there!
In this case, according to the given information, it turns out possible for us use the thermodynamic definition of the Gibbs free energy and its relationship with Ksp as follows:

Thus, by combining them, we obtain:

Which is related to the general line equation:

Whereas:

It means that we answer to the blanks as follows:
To determine the enthalpy and entropy of dissolving a compound, you need to measure the Ksp at multiple temperatures. Then, plot ln(Ksp) vs. 1/T. The slope of the plotted line relates to the enthalpy (ΔH) of dissolving and the intercept of the plotted line relates to the entropy (ΔS) of dissolving.
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