Answer:
The correct answer is entropy change of the surrounding plus the entropy change of the system must be positive.
Explanation:
The term entropy is a state function.Entropy can be defined as the disorder or randomness of the molecules in a system.
A spontaneous reaction is a type of reaction which deals with the release of free energy.The change of free energy in case of spontaneous reaction is always negative.
According to the second law of thermodynamics a spontaneous reaction will occur in a system if the total entropy of both system and surrounding increases during the reaction.
Answer:
Molar heat of solution of KBr is 20.0kJ/mol
Explanation:
Molar heat of solution is defined as the energy released (negative) or absorbed (Positive) per mole of solute being dissolved in solvent.
The dissolution of KBr is:
KBr → K⁺ + Br⁻
In the calorimeter, the temperature decreases 0.370K, that means the solution absorbes energy in this process. The energy is:
q = 1.36kJK⁻¹ × 0.370K
q = 0.5032kJ
Moles of KBr in 3.00g are:
3.00g × (1mol / 119g) = 0.0252moles
Thus, molar heat of solution of KBr is:
0.5032kJ / 0.0252moles = <em>20.0kJ/mol</em>
Answer:
A. 
B. 
Explanation:
Hello!
In this case, since the undergoing chemical reaction between nitrogen and hydrogen is:
Thus we proceed as follows:
A. Here, we first need to compute the moles of ammonia yielded by each reactant, in order to identify the limiting one:
Thus, since nitrogen yields the fewest moles of ammonia, we realize it is the limiting reactant, so the theoretical yield, in grams, of ammonia is:
B. Finally, since the actual yield of ammonia is 1.23, the percent yield turns out:
Best regards!
Answer:
185.05 g.
Explanation
Firstly, It is considered as a stichiometry problem.
From the balanced equation: 2LiCl → 2Li + Cl₂
It is clear that the stichiometry shows that 2.0 moles of LiCl is decomposed to give 2.0 moles of Li metal and 1.0 moles of Cl₂, which means that the molar ratio of LiCl : Li is (1.0 : 1.0) ratio.
We must convert the grams of Li metal (30.3 g) to moles (n = mass/atomic mass), atomic mass of Li = 6.941 g/mole.
n = (30.3 g) / (6.941 g/mole) = 4.365 moles.
Now, we can get the number of moles of LiCl that is needed to produce 4.365 moles of Li metal.
Using cross multiplication:
2.0 moles of LiCl → 2.0 moles of Li, from the stichiometry of the balanced equation.
??? moles of LiCl → 4.365 moles of Li.
The number of moles of LiCl that will produce 4.365 moles of Li (30.3 g) is (2.0 x 4.365 / 2.0) = 4.365 moles.
Finally, we should convert the number of moles of LiCl into grams (n = mass/molar mass).
Molar mass of LiCl = 42.394 g/mole.
mass = n x molar mass = (4.365 x 42.394) = 185.05 g.
