The partial pressure of a gas in a mixture follow the equation:

In case of air, at a total pressure of 1 atm, the partial fraction of nitrogen is 0,78, because

The partial pressure of nitrogen will be:
C. Sometimes
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Answer : The correct option is, (b) 22.5 M
Explanation : Given,
Mass of calcium nitrate tetrahydrate = 266 g
Molar mass of calcium nitrate tetrahydrate = 236.15 g/mole
Volume of solution = 
Molarity : It is defined as the moles of solute present in one liter of solution.
Formula used :

Now put all the given values in this formula, we get:

As calcium nitrate tetrahydrate dissociate to give 1 mole of calcium ion, 2 moles of nitrate ion and 4 moles of water.
The concentration of nitrate ion = 
Thus, the concentration of nitrate ion is, 22.5 M