d perovskite single crystals with suppressed ion migration for high-performance planar-type photodetectors, small

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3 0

Due to their improved charge transfer and great environmental stability, 2D Dion-Jacobson (DJ) perovskites have recently received a lot of attention.

Unfortunately, due to the scarcity of high-quality single crystals for precise measurements, their fundamental optoelectronic capabilities are mainly unknown. Here, a reactive, low-temperature-gradient crystallization method is created using 1,4-butanediammonium as a short-chain insulating spacer to generate high-quality 2D perovskite single crystal (BDAPbI4). It is discovered that the BDAPbI4 single crystal exhibits a direct bandgap with effective charge collection (μτ = 1.45 × 10−3 cm2 V−1). The BDAPbI4 single crystal in particular exhibits the expected high ion migration activation energy (0.88 eV).

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7 0

1 year ago

A 1.42-g sample of a pure compound with formula m2so4 was dissolved in water and treated with an ex- cess of aqueous calcium chl

solong [7]

The reaction between $m_{2}SO_{4}$ with calcium chloride can be shown as- $m_{2}SO_{4}$ + $CaCl_{2}$ → $CaSO_{4}$ ↓+2mCl. The molecular weight of $CaSO_{4}$ is 136.14g. The weight of sulfate ion is 96.06g. The molecular weight of $m_{2}SO_{4}$ = (2×m + 96.06). From the reaction we can see that 1 mole of calcium chloride reacts with 1 moles $m_{2}SO_{4}$ to produce 1 mole of calcium sulfate. Now 1.36g of calcium sulfate is equivalent to 1.36/136.14=9.989× $10^{-3}$ moles of calcium sulfate.