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2 years ago

What feature of an orbital is related to each of the following? (a) Principal quantum number (n)

1 answer:

6 0

Principle quantum number describes the energy of an electron and most probable distance of the electron from the nucleus.

<h3>What is the significance of principle quantum numbers and azimuthal quantum numbers?</h3>

A principal quantum number signifies size and energy of the orbital.Azimuthal quantum number signifies three dimensional shape of the orbital.

Magnetic quantum numbers signifies spatial orientation of the orbital.

Principal quantum numbers is the quantum numbers denoted by n which indirectly describes the size of the electron orbitals. It is always assigned an integer value but its value never be 0. The feature of a principal quantum numbers is the energy of an electron and most probable distance of the electron from the nucles.

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Suppose that a certain biologically important reaction is quite slow at physiological temperature (37 oC) in the absence of a ca

Oksi-84 [34.3K]

Answer:

30 kJ

Explanation:

Arrhenius equation is given by:

$k=Aexp(-Ea/RT)\\$

Here, k is rate constant, A is Pre-exponential factor, Ea is activation energy and T is temperature.

taking natural log of both side

ln k = ln A - Ea/RT

In Arrhenius equation, A, R and T are constant.

Therefore,

$ln\frac{k_2}{k_1} =\frac{Ea_1-Ea_2}{RT}$

$Ea_1-Ea_2$ is the lowering in activation energy by enzyme,

R = 8.314 J/mol.K

T = 37°C + 273.15 = 310 K

$\frac{k_2}{k_1} =1\times 10^5$

$ln 1\times 10^5 =\frac{Ea_1-Ea_2}{RT}\\{Ea_1-Ea_2} = 11.512 \times 8.314 \times 310\\=29670\ J\\=30\ kJ$

4 0

3 years ago

Sulfonation of benzene has the following mechanism: (1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3 [fast] (2) SO3 + C6H6 → H(C6H5+)SO3− [slow]

ziro4ka [17]

Question is incomplete, complete question is as follows :

Complete Question : .Sulfonation of benzene has the following mechanism:

(1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3

[fast]

(2) SO3 + C6H6 → H(C6H5+)SO3−

[slow]

(3) H(C6H5+)SO3− + HSO4− → C6H5SO3− + H2SO4

[fast]

(4) C6H5SO3− + H3O+ → C6H5SO3H + H2O

[fast]

write the overall rate law for the initial rate of the reaction as a fraction.

Rate=k(________/_________)

Answer:

The overall rate law for the initial reaction is = $k_{overall} [H_{2}SO_{4}]^{2} [C_{6}H_{6}]$

Explanation :

Frist of all, all the common terms are cancelled out and written the overall reaction.

As we know that the rate depednant step is the slowest step of the reaction, rate law is :

rate = $k_{2} [SO_{3}][C_{6}H_{6}]$

But the problem is that SO3 cannot be written in the overall rate law because it is an intermediate.

Rate law for synthesis of S03 is as follows :

rate = $k_{1}[H_{2}SO_{4}]^{2}$

Hence when we substitute equation 2 in equation one,

Rate comes out to be = $k_{overall} [H_{2}SO_{4}]^{2} [C_{6}H_{6}]$

6 0

3 years ago

Thermal energy always moves from a greater energy level to a lesser energy level

Nookie1986 [14]

Answer:

$\fbox{Law -Based \: on \: laws \: of \: thermodynamic}$

Explanation:

At constant pressure Thermal energy always moves from a greater energy level to a lesser energy level, laws of thermodynamics prove that.

Nature always likes to attain equilibrium either it's movement of heat energy or flow of water from higher region to lower region. The first and second law of thermodynamics are profe of that, the first law says that the total energy of universe is Constant. Energy can not be destroyed it always changes from one form to another, by work and heat. The second law explains why thermal energy moves from a greater energy level to a lesser energy level, it deals with the change in entropy of a system and surrounding and states heat flows from hot environment to cold environment.

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6 0

2 years ago

there are two processes involved in photosynthesis- the light reactions and the dark reactions- what is the end result of the li

GarryVolchara [31]

In light reactions there is successful photosynthesis due to the fact one of the primary reactants for photosynthesis in the first place. At the end of the light reaction, there will be the normal photosynthesis products formed which are glucose and oxygen. For the dark reaction no products will be formed

4 0

3 years ago

Entropy can be thought of as the degree of disorganization of a system.<br> TRUE<br> FALSE

Mice21 [21]

Answer:

True

Explanation:

The entropy of a system denoted by S is a thermodynamic function that increases in value when there are more ways to arrange the particles in the system. Some spontaneous chemical processes are entropy driven. An increase in entropy is said to drive the dissolution of ionic salts along with the evaporation of water are related to the spreading out of energy.

The entropy of a system can be taken as a measure of disorder of a system. In a spontaneous chemical process, the entropy of the universe is said to increase. ΔSunivu>0. Making the answer true.

7 0

3 years ago