Answer:
A. ΔG° = 132.5 kJ
B. ΔG° = 13.69 kJ
C. ΔG° = -58.59 kJ
Explanation:
Let's consider the following reaction.
CaCO₃(s) → CaO(s) + CO₂(g)
We can calculate the standard enthalpy of the reaction (ΔH°) using the following expression.
ΔH° = ∑np . ΔH°f(p) - ∑nr . ΔH°f(r)
where,
n: moles
ΔH°f: standard enthalpy of formation
ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g)) - 1 mol × ΔH°f(CaCO₃(s))
ΔH° = 1 mol × (-635.1 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1206.9 kJ/mol)
ΔH° = 178.3 kJ
We can calculate the standard entropy of the reaction (ΔS°) using the following expression.
ΔS° = ∑np . S°p - ∑nr . S°r
where,
S: standard entropy
ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g)) - 1 mol × S°(CaCO₃(s))
ΔS° = 1 mol × (39.75 J/K.mol) + 1 mol × (213.74 J/K.mol) - 1 mol × (92.9 J/K.mol)
ΔS° = 160.6 J/K. = 0.1606 kJ/K.
We can calculate the standard Gibbs free energy of the reaction (ΔG°) using the following expression.
ΔG° = ΔH° - T.ΔS°
where,
T: absolute temperature
<h3>A. 285 K</h3>
ΔG° = ΔH° - T.ΔS°
ΔG° = 178.3 kJ - 285K × 0.1606 kJ/K = 132.5 kJ
<h3>B. 1025 K</h3>
ΔG° = ΔH° - T.ΔS°
ΔG° = 178.3 kJ - 1025K × 0.1606 kJ/K = 13.69 kJ
<h3>C. 1475 K</h3>
ΔG° = ΔH° - T.ΔS°
ΔG° = 178.3 kJ - 1475K × 0.1606 kJ/K = -58.59 kJ
THE KINETIC MOLECULAR THEORY STATES THAT ALL PARTICLES OF AN IDEAL GAS ARE IN CONSTANT MOTION AND EXHIBITS PERFECT ELASTIC COLLISIONS.
Explanation:
An ideal gas is an imaginary gas whose behavior perfectly fits all the assumptions of the kinetic-molecular theory. In reality, gases are not ideal, but are very close to being so under most everyday conditions.
The kinetic-molecular theory as it applies to gases has five basic assumptions.
- Gases consist of very large numbers of tiny spherical particles that are far apart from one another compared to their size.
- Gas particles are in constant rapid motion in random directions.
- Collisions between gas particles and between particles and the container walls are elastic collisions.
- The average kinetic energy of gas particles is dependent upon the temperature of the gas.
- There are no forces of attraction or repulsion between gas particles.
Answer:
Increasing atomic number - True
Explanation:
The modern table is based on Mendeleev’s table, except the modern table arranges the elements by increasing atomic number instead of atomic mass.
The Atomic number is the number of protons in an atom, and this number is unique for each element. For example, Hydrogen has an atomic number of 1, Calcium has an atomic number of 20.
In the modern periodic table the elements are further arranged into:
- rows, called periods, in order of increasing atomic number. Elements in the same periods have the same number of shells.
- vertical columns, called groups, where the elements have similar properties. Elements in the same group has the same number of valency (outermost number of electrons)
Where are the following elements to choose from?