Question

Calculate the cfse for a d^3 system in an octahedral field in units of ∆_o. In other words, do not enter "∆_o" with your answer. For example, if your answer is −0. 8∆_o, then enter "−0. 8. ".

Answer 1

Magnetic moment (spin only) of octahedral complex having CFSE=−0.8Δo and surrounded by weak field ligands can be : Q

To answer this, the Crystal Field Stabilization Energy has to be calculated for a (d3 metal in both configurations. The geometry with the greater stabilization will be the preferred geometry. So for tetrahedral d3, the Crystal Field Stabilization Energy is: CFSE = -0.8 x 4/9 Δo = -0.355 Δo.

[Co(CN)64-] is also an octahedral d7 complex but it contains CN-, a strong field ligand. Its orbital occupancy is (t2g)6(eg)1 and it therefore has one unpaired electron. In this case the CFSE is −(6)(25)ΔO+(1)(35)ΔO+P=−95ΔO+P.

The crystal field stabilization energy (CFSE) (in kJ/mol) for complex, [Ti(H2O)6]3+. According to CFT, the first absorption maximum is obtained at 20,3000cm−1 for the transition.

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