1 Aluminium is oxidised Al - 3e = Al⁺³
2 Chlorine is reduced Cl⁺⁷ + 8e = Cl⁻¹
3 Nitrogen is oxidised 2N⁻³ - 6e = N₂
Hydrated salts are when salt crystals have water molecules bound. Anhydrous salts are when the water has been removed.
mass of water removed = hydrated salt - anhydrate salt
= 11.75 g - 9.25 g = 2.50 g
number of water moles = 2.50 g / 18 g/mol = 0.139 mol
number of cobalt (II) chloride moles = 9.25 g / 130 g/mol = 0.0712 mol
ratio of water moles to CoCl₂ moles - 0.139 mol / 0.0712 mol = 1.95
rounded off 2 moles of water for every 1 mol of CoCl₂
formula - CoCl₂.2H₂O
name - Cobalt(II) chloride dihydrate
Answer : All of the above are valid expressions of the reaction rate.
Explanation :
The given rate of reaction is,
The expression for rate of reaction for the reactant :
![\text{Rate of disappearance of }NH_3=-\frac{1}{4}\times \frac{d[NH_3]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20%7DNH_3%3D-%5Cfrac%7B1%7D%7B4%7D%5Ctimes%20%5Cfrac%7Bd%5BNH_3%5D%7D%7Bdt%7D)
![\text{Rate of disappearance of }O_2=-\frac{1}{7}\times \frac{d[O_2]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20%7DO_2%3D-%5Cfrac%7B1%7D%7B7%7D%5Ctimes%20%5Cfrac%7Bd%5BO_2%5D%7D%7Bdt%7D)
The expression for rate of reaction for the product :
![\text{Rate of formation of }NO_2=+\frac{1}{4}\times \frac{d[NO_2]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20%7DNO_2%3D%2B%5Cfrac%7B1%7D%7B4%7D%5Ctimes%20%5Cfrac%7Bd%5BNO_2%5D%7D%7Bdt%7D)
![\text{Rate of formation of }H_2O=+\frac{1}{6}\times \frac{d[H_2O]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20%7DH_2O%3D%2B%5Cfrac%7B1%7D%7B6%7D%5Ctimes%20%5Cfrac%7Bd%5BH_2O%5D%7D%7Bdt%7D)
From this we conclude that, all the options are correct.
They go through radioactive decay because when atoms are unstable by going through it they are emitting radiation in natural process and they gain stability by losing energy.
NaOH reacts with CH3COOH in 1:1 molar ratio to produce CH3COONa
NaOH + CH3COOH → CH3COONa + H2O
Mol CH3COOH in 52.0mL of 0.35M solution = 52.0/1000*0.35 = 0.0182 mol CH3COOH
Mol NaOH in 19.0mL of 0.40M solution = 19.0/1000*0.40 = 0.0076 mol NaOH
These will react to produce 0.0076 mol CH3COONa and there will be 0.0182 - 0.0076 = 0.0106 mol CH3COOH remaining in solution unreacted . Total volume of solution = 52.0+19.0 = 71mL or 0.071L
Molarity of CH3COOH = 0.0106/0.071 = 0.1493M
CH3COONa = 0.0076 / 0.071 = 0.1070M
pKa acetic acid = - log Ka = -log 1.8*10^-5 = 4.74.
pH using Henderson - Hasselbalch equation:
pH = pKa + log ([salt]/[acid])
pH = 4.74 + log ( 0.1070/0.1493)
pH = 4.74 + log 0.717
pH = 4.74 + (-0.14)
pH = 4.60.
